Complex Numbers in Wave Function: QM Explained

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Discussion Overview

The discussion revolves around the role of complex numbers, specifically the imaginary unit i, in quantum mechanics wave functions. Participants explore the implications of using complex exponentials versus real-valued functions in the context of the Schrödinger equation and wave behavior.

Discussion Character

  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • Some participants question the necessity of the complex number i in the wave function, suggesting that a real-valued exponential function could suffice.
  • Others argue that complex numbers are essential for normalizing wave functions and obtaining wave-like behavior, as real-valued functions do not allow for normalization.
  • A participant notes that without the imaginary unit, the function would not exhibit the periodic nature expected from wave phenomena and references the relationship between sine/cosine and exponential functions.
  • Another participant mentions that while parts of the wave function can resemble real exponentials, the entire wave function cannot be real-valued, particularly in the context of the WKB approximation and bound states.
  • Exponential decay is mentioned as relevant for certain decay processes, indicating the importance of complex solutions in various scenarios.

Areas of Agreement / Disagreement

Participants express differing views on the necessity and implications of using complex numbers in wave functions. There is no consensus on whether real-valued functions could adequately describe quantum behavior.

Contextual Notes

Limitations include the dependence on specific conditions such as potential energy scenarios (V > E vs. V < 0) and the normalization requirements of wave functions, which remain unresolved in the discussion.

Zaya Bell
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I just need to know. Why exactly what's the complex number i=√–1 put in the wave function for matter. Couldn't it have just been exp(kx–wt)?
 
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Zaya Bell said:
I just need to know. Why exactly what's the complex number i=√–1 put in the wave function for matter. Couldn't it have just been exp(kx–wt)?

It's not possible to normalize that kind of a real-valued exponential function. The Schroedinger equation is a complex diffusion equation, and the complex numbers make it possible to obtain wave-like behavior (wavepackets reflecting from walls, etc.) instead of the simple dissipative dynamics of ordinary diffusion where the solution is a real function.
 
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Is it a periodic function without the ##i## which we would expect from a wave? You may want to look up the connection between the sine (cosine) function and the exponential function.
 
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Zaya Bell said:
I just need to know. Why exactly what's the complex number i=√–1 put in the wave function for matter. Couldn't it have just been exp(kx–wt)?
Sure, you can have parts of the wavefunction look like exp(kx-wt), but not the whole thing. If you consider a WKB approximation for the time independent Schrödinger equation, you get solutions that look like
##\exp(\sqrt{2m(V-E)})##
which looks like an exponential where V > E and an oscillation where E > V. You aren't allowed to have V > E for the whole wavefunction, because, as hilbert2 noted, it is not possible to normalize. But, for a bound state of a delta potential (V < 0), you have a double exponential solution https://en.wikipedia.org/wiki/Delta_potential.

As far as the time part, you get exponential decay for various decay processes.
 
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Thank you all.
 

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