Convert Hamiltonian to matrix in weird basis

Click For Summary

Homework Help Overview

The discussion revolves around a quantum mechanics problem involving angular momentum, specifically the Hamiltonian of a system with l = 1. The original poster presents a Hamiltonian expressed in terms of the components of angular momentum in a specific basis, seeking assistance in converting this Hamiltonian into matrix form and understanding the stationary states and their energies.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning, Problem interpretation

Approaches and Questions Raised

  • Participants discuss the expressions for the angular momentum components L_u and L_v, with some suggesting relationships to L_x and L_z. There is uncertainty about how to express the Hamiltonian in matrix form and how to compute its effects on the basis states. Questions arise regarding the application of raising and lowering operators and the interpretation of the Hamiltonian's action on the states.

Discussion Status

Participants are actively exploring the relationships between the angular momentum operators and the Hamiltonian. Some have made progress in expressing L_u and L_v, while others are still grappling with the conversion to matrix form. There is a collaborative effort to clarify the steps needed to compute the Hamiltonian's effects on the basis states, with multiple interpretations being discussed.

Contextual Notes

There is an ongoing discussion about the assumptions made regarding the angular momentum operators and their representations. Participants express frustration with the lack of clear examples in their reference materials, indicating a need for further clarification on foundational concepts related to the problem.

emeriska
Messages
17
Reaction score
0
Hi guys,

I'm having a hard time with that one from Cohen-Tannoudji, ##F_{VI}## # 6. I'm translating from french so sorry if some sentence are weird or doesn't use the right words.

1. Homework Statement

We consider a system of angular momentum l = 1; A basis from it sub-space of states is constituted by these 3 eigenvectors of ##L_z : |1>, |0>, |-1>## of eigenvalues ##h, 0, -h## respectively.

This system, that has a electric quadrupolar moment, is submerged in an electric field gradient, so that the hamiltonian is:
##H = \frac{w_0}{h}(L_u^2-L_v^2)##

Where ##L_u## and ##L_v## are the components of ##L## on the 2 directions ##O_u## and ##O_v## of the plan ##xOz##, at 45 degree from ##Ox## and ##Oz##; ##w_0## is a real constant.

2. Question
a) Write down the matrix representing ##H## in the basis ##{ |1>, |0>, |-1>}##. What are the stationary states of the system and their energy? (These states will be named ##|E_1> |E_2> |E_3>## in crescent order of energy)

The Attempt at a Solution


I'm really stuck here. I don't know how to deal with the whole ##L_u, L_v## thing.

I assumed that ##L_u = \frac{L_x + L_z}{\sqrt{2}}## but I'm really not sure if that's the right assumption...

Also I'm having a hard time with the whole "Matrix" thing...not knowing how to convert in matrix :SThanks a lot for helping out!
 
Physics news on Phys.org
emeriska said:
Hi guys,

I'm having a hard time with that one from Cohen-Tannoudji, ##F_{VI}## # 6. I'm translating from french so sorry if some sentence are weird or doesn't use the right words.

1. Homework Statement

We consider a system of angular momentum l = 1; A basis from it sub-space of states is constituted by these 3 eigenvectors of ##L_z : |1>, |0>, |-1>## of eigenvalues ##h, 0, -h## respectively.

This system, that has a electric quadrupolar moment, is submerged in an electric field gradient, so that the hamiltonian is:
##H = \frac{w_0}{h}(L_u^2-L_v^2)##

Where ##L_u## and ##L_v## are the components of ##L## on the 2 directions ##O_u## and ##O_v## of the plan ##xOz##, at 45 degree from ##Ox## and ##Oz##; ##w_0## is a real constant.

2. Question
a) Write down the matrix representing ##H## in the basis ##{ |1>, |0>, |-1>}##. What are the stationary states of the system and their energy? (These states will be named ##|E_1> |E_2> |E_3>## in crescent order of energy)

The Attempt at a Solution


I'm really stuck here. I don't know how to deal with the whole ##L_u, L_v## thing.

I assumed that ##L_u = \frac{L_x + L_z}{\sqrt{2}}## but I'm really not sure if that's the right assumption...

Also I'm having a hard time with the whole "Matrix" thing...not knowing how to convert in matrix :SThanks a lot for helping out!

You're not really stuck, yet. You have a correct expression for L_u. Get a similar one for L_v, and figure out the Hamiltonian and its effect on the basis states.
 
So I figured ##L_v = \frac{L_z - L_x}{\sqrt{2}}##

But I don't see how to convert that into a matrix. We use Griffiths and I feel like my book is not really helping me on that :S
 
emeriska said:
So I figured ##L_v = \frac{L_z - L_x}{\sqrt{2}}##

But I don't see how to convert that into a matrix. We use Griffiths and I feel like my book is not really helping me on that :S

A matrix is just a way to organize a system of equations. There is nothing fundamental about it. If you compute the Hamiltonian H in terms of L_x, L_y, L_z, then you will find that:

H | -1 \rangle = \alpha_1 | -1 \rangle + \beta_1 | 0 \rangle + \gamma_1 | +1 \rangle
H | 0 \rangle = \alpha_2 | -1 \rangle + \beta_2 | 0 \rangle + \gamma_2 | +1 \rangle
H | +1 \rangle = \alpha_3 | -1 \rangle + \beta_3 | 0 \rangle + \gamma_3 | +1 \rangle

You can compute the values \alpha_i, \beta_i, \gamma_i. Then you can think of these as a matrix equation as follows:

Let \left( \begin{array}& u \\ v \\ w \end{array} \right) represent the state u | -1 \rangle + v | 0 \rangle + w | +1 \rangle. Then the action of H on such a matrix is given by:

H \left( \begin{array}& u \\ v \\ w \end{array} \right) = \left( \begin{array}& \alpha_1 & \alpha_2 & \alpha_3 \\ \beta_1 & \beta_2 & \beta_3 \\ \gamma_1 & \gamma_2 & \gamma_3 \end{array} \right) \left( \begin{array}& u \\ v \\ w \end{array} \right)

As I said, matrices is just a way to organize the equations.
 
I read this section of my book at least 100 times and I still have no idea how to start this problem. If I start with what you just gave me, how can I compute the values ##\alpha , \beta , \gamma## ? Of maybe you know somewhere else where that is explained?
 
emeriska said:
I read this section of my book at least 100 times and I still have no idea how to start this problem. If I start with what you just gave me, how can I compute the values ##\alpha , \beta , \gamma## ? Of maybe you know somewhere else where that is explained?

Well, your Hamiltonian is a combination of factors of L_x, L_y, L_z. Do you know how L_x acts on |+1\rangle and on |0\rangle and |+1\rangle? What about L_y? What about L_z?

Have you learned about raising and lowering operators for angular momentum?
 
Yes I do know about raising and lowering operators, that I guess I will have to find in terms of $L_u, L_v$ right?

But I'm stuck at the very basic. I don't know where to start to write $H$ in a basis. I can't find any example on the web that is even remotely similar to this question.

Thanks for you help by the way, really appreciated.
 
emeriska said:
Yes I do know about raising and lowering operators, that I guess I will have to find in terms of $L_u, L_v$ right?

But I'm stuck at the very basic. I don't know where to start to write $H$ in a basis.

Yes, you know everything you need to know about H. You know how to write it in terms of L_u and L_v, and you know how to write L_u and L_v in terms of L_x and L_z. And you know how to write L_x in terms of L_+ and L_-. Right? So put it all together to get H in terms of L_+ and L_-.

The equations that you need:

  1. L_u = \frac{1}{\sqrt{2}} (L_z + L_x)
  2. L_v = \frac{1}{\sqrt{2}} (L_z - L_x)
  3. L_x = \frac{1}{2} (L_+ + L_-)
  4. H = \frac{w_0}{\hbar}((L_u)^2 - (L_v)^2)
So before you do anything else, write down H in terms of L_z, L_+ and L_-. Post the answer.
 
  • Like
Likes   Reactions: emeriska
If my calculus are right I should have ##H = \frac{w_0}{\hbar} L_z(L_++L_-)##
 
  • #10
emeriska said:
If my calculus are right I should have ##H = \frac{w_0}{\hbar} L_z(L_++L_-)##

That's not what I got. I got H = \frac{w_0}{\hbar} (L_x L_z + L_z L_x) = \frac{w_0}{2\hbar} (L_+ L_z + L_- L_z + L_z L_+ + L_z L_-). I may have made a mistake, also.

But next, compute what the effect of H is on the three states |-1\rangle, |0\rangle, |+1\rangle

Use the following rules:

L_+ |m\rangle = \sqrt{l(l+1) - m(m+1)} |m+1\rangle
L_- |m\rangle = \sqrt{l(l+1) - m(m-1)} |m-1\rangle
L_z |m\rangle = m |m\rangle

where m=-1, 0, +1 and where l=1

So compute H|-1\rangle, H|0\rangle, H|+1\rangle
 
  • #11
You were right on the equation of ##H##
So, I have

L_+ |-1\rangle = \sqrt{2} |0\rangle
L_+ |0\rangle = \sqrt{2} |1\rangle
L_+ |1\rangle = 0 |2\rangle

L_- |-1\rangle = 0 |-2\rangle
L_- |0\rangle = \sqrt{2} |-1\rangle
L_- |1\rangle = \sqrt{2} |0\rangle

L_z |-1\rangle = - |-1\rangle
L_z |0\rangle = 0|0\rangle
L_z |1\rangle = |1\rangleSo that H|-1\rangle, H|0\rangle, H|+1\rangle would look like this:

##H|-1\rangle = \frac{w_0}{2\hbar}(\sqrt{2}|0\rangle(-)|-1\rangle+(-)|-1\rangle\sqrt{2}|0\rangle)##

And etc for the other ##H## right?

And then I use the matrix convertion stuff you gave me a couple posts back?

How do I deal with a multiplication of ##|m\rangle## states?
 
Last edited:
  • #12
I just edited that last post because you were right for the equation of ##H##
 
Last edited:
  • #13
emeriska said:
You were right on the equation of ##H##
So, I have

L_+ |-1\rangle = \sqrt{2} |0\rangle
L_+ |0\rangle = \sqrt{2} |1\rangle
L_+ |1\rangle = 0 |2\rangle

L_- |-1\rangle = 0 |-2\rangle
L_- |0\rangle = \sqrt{2} |-1\rangle
L_- |1\rangle = \sqrt{2} |0\rangle

L_z |-1\rangle = - |-1\rangle
L_z |0\rangle = 0|0\rangle
L_z |1\rangle = |1\rangle

Right, except 0 times anything is still 0.

So that H|-1\rangle, H|0\rangle, H|+1\rangle would look like this:

##H|-1\rangle = \frac{w_0}{2\hbar}(\sqrt{2}|0\rangle(-)|-1\rangle+(-)|-1\rangle\sqrt{2}|0\rangle)##

I don't know what you're doing there. H has 4 terms:
\frac{w_0}{2\hbar} L_+ L_z
\frac{w_0}{2\hbar} L_- L_z
\frac{w_0}{2\hbar} L_z L_+
\frac{w_0}{2\hbar} L_z L_-

What is L_+ L_z |-1\rangle?
What is L_- L_z |-1\rangle?
What is L_z L_+ |-1\rangle?
What is L_z L_-|-1\rangle?

(Note, there is only 1 of those 4 that is nonzero)

Add them all together, multiply by \frac{w_0}{2\hbar}, and that gives you H |-1\rangle
 
  • #14
emeriska said:
How do I deal with a multiplication of ##|m\rangle## states?

That doesn't happen.

Let me just work out one example: L_z L_+ |-1\rangle = L_z (L_+ |-1\rangle) = L_z( \sqrt{2} |0\rangle) = \sqrt{2} (L_z |0\rangle) = \sqrt{2} \cdot 0 \cdot |0\rangle = 0
 
  • #15
OH! I see! Rhat's not what I was doing at all. Thanks a lot, I'll see where this leads me
 
  • #16
H \Psi = \left( \begin{array}& 0 & \sqrt{2} & 0 \\ -\sqrt{2}& 0 & \sqrt{2} \\ 0 & \sqrt{2} & 0 \end{array} \right) \Psi

Thanks a lot! I guess I only have to find the stationary states from this matrix?

The stationary states would be the line vectors of the matrix is that right? So something like ##\frac{w_0}{2\hbar}\sqrt{2}|-1>## for the first one...

And I guess to find their energy I have to write down ##H\Psi=E\Psi## with H being my matrix and ##\Psi## the vector? Not quite sure about that either...
 
  • #17
emeriska said:
H \Psi = \left( \begin{array}& 0 & \sqrt{2} & 0 \\ -\sqrt{2}& 0 & \sqrt{2} \\ 0 & \sqrt{2} & 0 \end{array} \right) \Psi

I think it's something like that (you left off the w_0 and \hbar, but that's easily fixable).

Thanks a lot! I guess I only have to find the stationary states from this matrix?

The stationary states would be the line vectors of the matrix is that right? So something like ##\frac{w_0}{2\hbar}\sqrt{2}|-1>## for the first one...

And I guess to find their energy I have to write down ##H\Psi=E\Psi## with H being my matrix and ##\Psi## the vector? Not quite sure about that either...

Now your problem has been reduced to solving an eigenvalue-eigenvector problem involving matrices. Have you studied that?
 
  • #18
Well I tried something but never got to the energies...anyway, my deadline was tomorrow so I should have the solutions by the weekend.

I certainly won't have 100% but if I have anything more than 0 it will be because of you! Thank you very much for your time, much appreciated! You helped me a lot!
 

Similar threads

  • · Replies 0 ·
Replies
0
Views
2K
  • · Replies 13 ·
Replies
13
Views
3K
  • · Replies 3 ·
Replies
3
Views
2K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 4 ·
Replies
4
Views
2K
  • · Replies 7 ·
Replies
7
Views
3K
  • · Replies 3 ·
Replies
3
Views
2K
  • · Replies 2 ·
Replies
2
Views
2K
  • · Replies 5 ·
Replies
5
Views
3K
  • · Replies 14 ·
Replies
14
Views
3K