The atmosphere of Venus is almost entirely CO2, but Venus is (from spacecraft observations) compositionally very similar to the Earth, including its Carbon abundance. The crust + atmosphere of Venus contains almost the same amount of Carbon as does the crust + oceans + atmosphere of the Earth. It's just that on Venus, there are no oceans, and all of the crustal Carbon has been driven into the atmosphere. It is, as far as we can tell, exactly what would happen if you warmed the surface of the Earth to 460 C, boiling the Oceans away and burning all of the soil, limestone, marble, etc., into CO2, which then would go into the atmosphere. (The surface of Venus is mostly quartz (SiO2) and other mineral oxides; i.e., lots of Oxygen, little or no Carbon.)
So, there is no reason, from the spacecraft exploration of Venus, to believe it is a Carbon planet, and excellent reasons to conclude that it isn't.