Crystal diffraction using Bragg's Law

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SUMMARY

The discussion focuses on calculating the longest possible wavelength of X-rays to reveal the (211) Bragg peak of a cubic crystal structure with a side length of 0.3 nm using Bragg's Law. The relevant equations are nλ = 2dSinθ and d = a/sqrt(h^2 + k^2 + l^2). The calculated d-spacing for the (211) plane is approximately 0.141 nm, leading to a maximum wavelength of 0.282 nm when θ is set to 90 degrees. Participants also seek clarification on determining the angle θ and the appropriate n value for calculations.

PREREQUISITES
  • Understanding of Bragg's Law (nλ = 2dSinθ)
  • Knowledge of cubic crystal structures and Miller indices
  • Ability to perform basic trigonometric calculations
  • Familiarity with X-ray diffraction techniques
NEXT STEPS
  • Research the calculation of d-spacing for different Miller indices in cubic crystals
  • Learn about the significance of the n value in Bragg's Law
  • Explore the relationship between X-ray wavelength and diffraction angles
  • Study practical applications of powder X-ray diffraction (XRD) in material science
USEFUL FOR

Students and researchers in materials science, crystallography, and solid-state physics who are studying X-ray diffraction and its applications in analyzing crystal structures.

frederer
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Homework Statement



You wish to study a material with a cubic crystal structure with
three orthogonal sides of length a = 0.3nm. What is the
longest possible wavelength of the X-ray source you could use
to reveal the (211) Bragg peak of the crystal?


Homework Equations



nλ = 2dSinθ (Bragg's Law)

d = a/sqrt(h^2 + k^2 + l^2)

The Attempt at a Solution



Hi. Ok so i think i need the two formulae above to solve this question.

You can figure out d simply enough by slotting in the numbers,
giving λ = 2.44Asinθ
but the trouble I am having is how to calculate the angle θ. If you draw out the
cube in question you can see the angles formed between in the plane but
I am not sure which angle, if one of these angles at all is required to solve
the question. Any help would be much appreciated.
 
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Dear all
i am struggling on a question regarding powder XRD. Can anybody please help me on this.

Question: I have lambda(X-ray wavelength used) and 2theta(100% intense peak) value of a crystal compound; with that data can anyone calculate the "d(distance between two planes)" value of that crystal using braggs law(i.e. nλ = 2 d sinΘ) theoritically. If so please explain me with an example.
Note: What is the n value we need to apply in that formula.
 

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