Cylinder,piston termodynamics problem

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Homework Help Overview

The problem involves a closed vertical cylinder with a mobile piston dividing it into two chambers containing an ideal gas. The initial volume ratio of the chambers is given as V1/V2=3, and both chambers are heated to a new temperature of 4T/3. The objective is to find the ratio of the new volumes after heating.

Discussion Character

  • Exploratory, Assumption checking, Conceptual clarification

Approaches and Questions Raised

  • Participants discuss the implications of the piston's mass being negligible versus non-negligible, questioning how this affects pressure equilibrium. There are attempts to derive relationships between pressures and volumes based on the ideal gas law and equilibrium conditions. Some participants suggest focusing on the net forces acting on the piston and how they relate to the final state after heating.

Discussion Status

The discussion is ongoing, with various interpretations of the problem's conditions being explored. Some participants have provided equations and relationships that could guide further analysis, while others express confusion about the assumptions regarding the piston's mass and its impact on the system.

Contextual Notes

There is uncertainty regarding the assumptions about the piston's mass and whether it is frictionless. Participants are also considering the implications of the initial equilibrium state and how it affects the final conditions after heating.

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Homework Statement


A closed vertical cylinder contains a mobile piston that splits it in two parts of volumes V1 and V2 with a ratio V1/V2=3. Both parts contain the same mass of an ideal gas at the same temperature T.
Both chambers are heated to a temperature of 4T/3, find the ratio of the new volumes.

Here's a little diagram to make it more clear.
diagram.PNG


The Attempt at a Solution



Now I'm somehow confused because they don't specify if the mass of the piston is negligible.

So, if the piston is in equilibrium and its mass is negligible then the resultant force that apply to the piston must be 0 => p1=p2, which is false because p1/p2=1/3. (where p=pressure)

If the piston's mass is not negligible it has a mass m.

p2=p1+mg/S
p2'=p1'+mg/S (where g=gravitational constant, S=surface area of the piston)

p2'-p1'=p2-p1
4nRT1/3 (1/V2' - 1/V1') = nRT1(1/V2-1/V1)

4/3 ( 1/V2' - 1/V1') = 1/V2 - 1/V1, from this i should conclude the V1'/V2' ratio but something might be wrong here, the problem statement is kind of misleading.
 
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Well, I am no thermodynamics kind of guy so take my comments with a grain of salt

First of all, this is some kind of idealized textbook problem, in other words, don't worry too much about mass vs mass-less or even gravity...' cause then, you would need to worry about friction or where is the rest of that piston which look pretty much like just a disc with no mechanism to be moved or anything...anyway...

If the initial condition was an equilibrium condition, I would say, yes, you need to find out how much pressure the piston is helping with to the weakest of the chambers...then, you keep that piston help constant and heat up both chambers and see what the final volumes need to be so the pressure still balance.

On the other hand, if the initial condition has nothing to do with anything and was not even steady and the piston is massless and is not exerting any force, then, the final position of the piston should be right in the middle... :-)
 
You know that there is a net downward force of the piston from the pressure difference. If it is frictionless, you could calculate the mass of the piston if you knew the area, but you don't need that. You just need to know that there is a net downward force that is constant (ie. the same force applies on the lower section after the contents are heated).

AM
 
Andrew Mason said:
You know that there is a net downward force of the piston from the pressure difference. If it is frictionless, you could calculate the mass of the piston if you knew the area, but you don't need that. You just need to know that there is a net downward force that is constant (ie. the same force applies on the lower section after the contents are heated).

AM

The piston is frictionless.

And that's pretty much what i said in the second part: p2=p1+mg/S where mg/S is due to the piston's mass. But i cannot find the ratio V1'/V2' from my calculations. I would really apprecied if you checked them.
Thanks.
 
Last edited:
I think you just need to come up with enough equations to find the ratio between the volumes after heating things up to 4T/3

For example, initially, you know that
(1) V1/V2 = 3
which can also be expressed as
(2) V1 - 3V2 = 0

Because both chambers have the same amount of mass and are at the same temperature, you know that
P1V1 = nRT = P2V2
and, thus
(3) P1V1 = P2V2
(4) P1/P2 = V2/V1
(5) P2/P1 = V1/V2
(6) P2/P1 = 3 [ using (1) ]
(7) P2 = 3P1
(8) P2 = P1 + 2P1

Also, because of the initial equilibrium condition, you know that
(9) P2 = P1 + Ppiston

See the similarity between (8) and (9) ? We now know the pressure that comes from the piston without having to know its mass or anything, we got it in terms of P1!

So, you need to continue with the problem and keep Ppiston constant.

After heating things up, you know have

(10) P1' V1' = 4nRT/3 = P2' V2'

And you also now have:

(11) P2' = P1' + Ppiston
(12) P2' = P1' + 2P1

And of course
(13) V1 + V2 = Vtotal
(14) V1' + V2' = Vtotal
and so
(15) V1 + V2 = V1' + V2'

etc., etc.
 

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