So the car itself is not mechanically decelerating (braking), you are essentially just traveling down the road at some constant speed and then want to know what the deceleration rate is if the accelerator is removed and the car slows down under the force of friction between it and the road surface?What is 'd'? Deceleration? If you are trying to model the car-road system as a solid mass (the car) moving on a stationary surface (the road), then your deceleration will be decided by the frictional force opposing your direction of motion and the mass of the car.
F = m*a
and also
F = u*mg
mg is the weight of the car, and assuming the road is flat this is the normal force exerted by the road onto the car. Frictional force is the product of the coefficient of static friction and the normal force. Assuming no other forces are acting on your car, you can say
m*a = u*mg
a = u*g
So your deceleration is given by the product of g and the coefficient of friction. So at least using that model of the car-road system your work seems correct.
To answer your question about whether this is ALWAYS the way to work the problem, though...in general yes. But you have to keep in mind that the normal force is not always just m*g. If the road is at some angle then you need to deal with force components in the normal direction and whatnot and do a little more work, but nothing major.