Derivation for Time to Max Radioactivity Transient Equilibrium

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SUMMARY

The discussion focuses on deriving the time to maximum activity (tm) for transient equilibrium in a parent-daughter radioactive decay scenario, specifically involving Mo-99 and Tc-99m. The formula presented for tm is (1 / (λ1-λ2)) * ln(λ1/λ2). Participants highlight the use of Bateman equations to derive the time it takes for Tc-99m to reach its maximum activity, which is approximately 24 hours. The conversation emphasizes the importance of understanding the decay constants and half-lives of both parent and daughter isotopes in this context.

PREREQUISITES
  • Understanding of radioactive decay principles
  • Familiarity with decay constants (λ1 and λ2)
  • Knowledge of half-life calculations
  • Experience with Bateman equations
NEXT STEPS
  • Study the derivation of the Bateman equations for multiple decay processes
  • Learn how to calculate decay constants from half-lives
  • Research transient equilibrium in radioactive decay systems
  • Explore applications of Mo-99 and Tc-99m in medical imaging
USEFUL FOR

This discussion is beneficial for nuclear physicists, radiochemists, and medical professionals involved in radioisotope applications, particularly those working with decay processes and transient equilibrium in radioactive materials.

matthewt
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Hi,

I'm having a bit of difficulty deriving the time to max activity for the case of transient equilibrium for a parent-daughter.

This is where I want to get to , tm = (1 / (λ1-λ2)) * 1n(λ1/λ2)

I believe there is an alternative equation for tm as well expressed in terms of half-life.

I would be gratefeul if someone could walk me through a derivation,

BW,
Matt
 
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Do you mean that you have some parent substance, with a given half-life time, which produces some daughter substance, with another given half-life time (which then decays into an inactive substance), and you need to find out the time it gets for the mix to attain maximum activity?
 
that's right. For the case of a Mo-99 and Tc-99m generator, at t=0, let the activity of Tc-99m be zero. The activity of Tc99m will increase until it reaches a maximum value, but will then start to decline as per transient equilibrium. I think using the bateman equations you can derive an expression for Tmax, the time it takes for the Tc-99m to reach it's max activity (which is ~ 24 hours). A derivation of that equation is what I'm after.

thanks,
matt
 
Do you understand how the single-step decay equation is obtained and solved?
 

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