Derive the van der Waal interaction between 2 spheres.

Click For Summary
SUMMARY

The discussion focuses on deriving the van der Waals interaction potential between two spheres using the Hamaker approach. Participants emphasize the importance of a double volume integration of the densities of the spheres and the constant 'c' over the distance 'r' raised to the sixth power. Key references include a detailed PDF on van der Waals forces and the original 1937 paper by Hamaker, which provides foundational equations for this derivation. Mathematica is recommended as a useful tool for performing the necessary calculations.

PREREQUISITES
  • Understanding of van der Waals forces
  • Familiarity with the Hamaker approach
  • Knowledge of volume integration techniques
  • Proficiency in using Mathematica for mathematical computations
NEXT STEPS
  • Study the mathematical derivation of van der Waals forces in the provided PDF
  • Learn about the Hamaker constant and its significance in interactions
  • Explore advanced integration techniques relevant to physics
  • Practice using Mathematica for solving complex integrals
USEFUL FOR

Researchers in physical chemistry, materials scientists, and anyone interested in the theoretical aspects of intermolecular forces, particularly in applications involving spherical particles.

Red
Messages
19
Reaction score
0
Hi guys, I need some help on this question:

Derive the van der Waal interaction potential between 2 spheres of radius R_1 and R_2 using the Hamaker approach. Take the distance between the center of each sphere to be D.

Thank you very much for your help!
 
Physics news on Phys.org
Read this:

http://dept.lamar.edu/chemicalengineering/www/tadmor/papers/vanderwaalsforces/vdw1.pdf

Could you explain me a little bit more about that?
Or some reference?
I know nothing about it.

Is the van der Waal interaction a starting point, or is it a consequence?
Is there a short (fast) derivation for formula (1) somewhere available?

Interresting because of the geeko.
 
Last edited by a moderator:
The Hamaker approach assume a pairwise addition, so the derivation start with a double volume integration of density_1 and density_2 and c over r^6, where r is the separation between the small volume in the integration, and c is a constant. Not sure if I make myself clear here.

Maybe this pdf will help, please refer to page 2, equation (1) for the mathematical description of what I had describe above. Thanks! Here is the link: http://chemeng.queensu.ca/courses/CHEE460/lectures/documents/CHEE4602010Lecture4.pdf

And yes the gecko is a master of VDW forces!
 
Last edited by a moderator:
I don't know if it is helpfull, but here is a link to the original paper by Hamaker:

http://www.utwente.nl/tnw/pcf/education/jmbc_course_on_capillarity_driv/Articles/anton_darhuber/surface_tension_etc/Hamaker_Physica1937_vdW_attract_spherical_particles.pdf

It is a little bit lengthy and even boring.
It looks like it is only about calculating the integral of formula (1) in the paper.
Probably a piece of cake if you have 1 hour free and Mathematica.

Thanks for the reference: it is very clear and readable.
 
Last edited by a moderator:
Thank you for your help. Mathematica does help.
 

Similar threads

Replies
1
Views
2K
  • · Replies 4 ·
Replies
4
Views
1K
  • · Replies 5 ·
Replies
5
Views
2K
  • · Replies 1 ·
Replies
1
Views
2K
Replies
9
Views
2K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 7 ·
Replies
7
Views
3K
  • · Replies 6 ·
Replies
6
Views
3K
Replies
8
Views
3K
Replies
2
Views
4K