The Maxwell's equations, are differential equations and no laws in the true sense. People just don't seem to get that!?
On the other hand, the Lorentz force law, the Coulomb's law, the Biot-Savart's law, the Faraday's law of induction as well as the conservation of charge are the fundamental laws of electromagnetics. These are experimental facts and can't be derived. From these you derive the Maxwell's equations in vacuum.
If you know the curl and and divergence of say the electric field E as well as the boundary conditions then you can also determine the E-field uniquely. This is the Helmholtz theorem. So we need one equation with the curl of B, and another independent one with divergence of B and similarly for E.
To derive Ampere-Maxwell's law we can start in magnetostatics. This is because we know that B is given by the Biot-Savart's law which one can start further develop to the general case (dynamic fields). For this we start by taking the curl of B, that is the curl of Biot-Savart's law. Applying some vector calculus to that will give you
[itex]\nabla\times\mathbf{B} = \mu_o\mathbf{J}[/itex]
The above has to satisfy continuity equation (conservation of charge). Applying the continuity equation gives
[itex]\nabla\times\mathbf{B} = \mu_o\mathbf{J} + \mu_0\epsilon_0\frac{\partial\mathbf{E}}{\partial t}[/itex]
That's the equation for vacuum. In matter you've maybe seen (and derived) the experssions for the polarization and the magnetization. Applying these give you the Ampere-Maxwell's equation in matter.
I know that many books in electromagnetics just post the Maxwell's equations in beginning claiming "this is how it is". I first learned electromagnetics from Griffiths' text, and he doesn't give you the Maxwell's equations until chapter 7. Instead he slowly derives the Maxwell's equations throughout the book. So I recommend Griffiths' book.