Deriving Tanabe Sugano diagram

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SUMMARY

The Tanabe-Sugano diagram is derived using Hans Bethe's crystal field theory and Giulio Racah's linear combinations of Slater integrals, known as Racah parameters. Understanding these foundational concepts is essential for grasping the derivation of the diagram. The discussion emphasizes the importance of studying these theories in detail to fully comprehend the Tanabe-Sugano diagram's implications in theoretical chemistry.

PREREQUISITES
  • Hans Bethe's crystal field theory
  • Slater integrals
  • Racah parameters
  • Theoretical chemistry fundamentals
NEXT STEPS
  • Study Hans Bethe's crystal field theory in detail
  • Explore Slater integrals and their applications
  • Learn about Racah parameters and their significance
  • Review advanced theoretical chemistry resources on Tanabe-Sugano diagrams
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Theoretical chemists, students in chemistry programs, and anyone interested in the derivation and application of Tanabe-Sugano diagrams in coordination chemistry.

bearcharge
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Hi all,

As a beginning theoretical chemist, I'm trying to understand how Tanabe-Sugano diagram was derived. Can someone help me understand the derivation in a nutshell? Thanks!
 
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Thank you for the suggestions. I was trying to understand how it is derived. In wikipedia, it says "They used Hans Bethe's crystal field theory and Giulio Racah's linear combinations of Slater integrals, now called Racah parameters..." so I guess I'd better start with Hans Bethe's crystal field theory, Slater integrals and Racah parameters... there is no shortcut if I really want to understand it... Thanks!
 

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