Deriving the cooridinate numbers of both ions in rock salt

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SUMMARY

The discussion focuses on deriving the coordinate numbers of ions in rock salt, specifically LiCl and NaCl, and comparing their lattice enthalpy values. The lattice enthalpy values provided are LiCl (861 kJ/mole), NaCl (787 kJ/mole), LiF (1046 kJ/mole), and MgO (3850 kJ/mole). A coordinate number is defined as the number of atoms surrounding a central atom in a solid-state lattice, and it is suggested that LiCl has a larger lattice energy due to the greater electronegativity difference between its constituents.

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rastamanrm
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How would I go about deriving the cooridinate numbers of both ions in rock salt, and,
how could I account for the differences in lattice enthalpy between the following;


LiCl (861 kJ/mole) - NaCl (787)
LiCl - LiF (1046)
LiCl - MgO (3850)

Cheers.
 
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rasta,

We can not help until you first show us what effort you have made. Please read the posting guidelines (see "Rules" on top of page).
 
Gokul43201 said:
rasta,

We can not help until you first show us what effort you have made. Please read the posting guidelines (see "Rules" on top of page).

Well I do know that a coordinate number is the number of atoms surrounding an atom in a solid state lattice

And for the second bit, I assume LiCl would have a larger lattice energy due to the greater difference in electronegativity of both consituents, similar with the next one. Not sure about the last one.
 

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