Determine density of states from an XPS spectrum

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SUMMARY

The density of states (DOS) can be accurately determined from an X-ray photoelectron spectroscopy (XPS) spectrum, particularly through energy-resolved photoelectron spectroscopy. Angle-resolved photoelectron spectroscopy (ARPES) provides the band structure, which can be projected onto the energy axis to yield the DOS. However, this method primarily reveals occupied states; to investigate unoccupied states, inverse photoelectron spectroscopy (IPES) is necessary, where an electron is captured into an unoccupied state, emitting a photon with measurable energy.

PREREQUISITES
  • X-ray photoelectron spectroscopy (XPS)
  • Energy-resolved photoelectron spectroscopy
  • Angle-resolved photoelectron spectroscopy (ARPES)
  • Inverse photoelectron spectroscopy (IPES)
NEXT STEPS
  • Research the principles and applications of X-ray photoelectron spectroscopy (XPS)
  • Explore energy-resolved photoelectron spectroscopy techniques
  • Study angle-resolved photoelectron spectroscopy (ARPES) and its data interpretation
  • Learn about inverse photoelectron spectroscopy (IPES) and its role in probing unoccupied states
USEFUL FOR

Researchers in material science, physicists studying electronic properties, and anyone involved in surface analysis using X-ray photoelectron spectroscopy.

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I've heard any many places that the density of states (DOS) can be determined from an x-ray photoelectron spectroscopy (XPS) spectrum.

Perhaps someone more knowledgeable than me can explain how this is done, or can direct me to a good resource?

Thanks!
 
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Energy-resolved photoelectron spectroscopy gives almost exactly the DOS. Angle-resolved PES (ARPES) gives the band structure (which can be projected onto the energy axis to give the DOS). Strictly speaking, this conventionally gives only the occupied states and one must do inverse PES (where an electron is captured into an unoccupied state and gives off a photon with measured energy) to probe the unoccupied states.
 

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