Determine density of states from an XPS spectrum

abstracted6
Messages
37
Reaction score
0
I've heard any many places that the density of states (DOS) can be determined from an x-ray photoelectron spectroscopy (XPS) spectrum.

Perhaps someone more knowledgeable than me can explain how this is done, or can direct me to a good resource?

Thanks!
 
Physics news on Phys.org
Energy-resolved photoelectron spectroscopy gives almost exactly the DOS. Angle-resolved PES (ARPES) gives the band structure (which can be projected onto the energy axis to give the DOS). Strictly speaking, this conventionally gives only the occupied states and one must do inverse PES (where an electron is captured into an unoccupied state and gives off a photon with measured energy) to probe the unoccupied states.
 
From the BCS theory of superconductivity is well known that the superfluid density smoothly decreases with increasing temperature. Annihilated superfluid carriers become normal and lose their momenta on lattice atoms. So if we induce a persistent supercurrent in a ring below Tc and after that slowly increase the temperature, we must observe a decrease in the actual supercurrent, because the density of electron pairs and total supercurrent momentum decrease. However, this supercurrent...
Hi. I have got question as in title. How can idea of instantaneous dipole moment for atoms like, for example hydrogen be consistent with idea of orbitals? At my level of knowledge London dispersion forces are derived taking into account Bohr model of atom. But we know today that this model is not correct. If it would be correct I understand that at each time electron is at some point at radius at some angle and there is dipole moment at this time from nucleus to electron at orbit. But how...
Back
Top