Determining an empirical formula

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SUMMARY

This discussion focuses on converting decimal ratios of atomic weights into empirical formulas. The key method involves expressing decimal numbers as fractions of small integers, such as converting 1.25 to 5/4 and 0.67 to 2/3. Once these fractions are established, multiplying by a common whole number yields whole-number coefficients necessary for the empirical formula. The discussion emphasizes that for introductory chemistry problems, the results should consistently yield small whole numbers, indicating accurate calculations.

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  • Understanding of atomic weight percentages
  • Basic knowledge of fractions and ratios
  • Familiarity with empirical formulas in chemistry
  • Introductory chemistry concepts
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  • Learn how to convert decimal numbers to fractions using the method of continued fractions
  • Study the process of deriving empirical formulas from molecular formulas
  • Explore the concept of mole ratios in chemical reactions
  • Investigate common errors in stoichiometric calculations
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Chemistry students, educators, and anyone involved in chemical analysis or empirical formula derivation.

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If I know the percentage by weight of elements in a formula I can calculate the relative ratios of atoms in the formula no problem.

What I can't figure out is how to turn that ratio into an empirical formula.

To put it mathematically how do I turn a decimal number into a an approximate fraction of small integers?

#.## = ?/?

Thanks
 
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You should be able to write those decimal numbers as the ratio of small whole numbers.*** For example, 1.25=5/4, 0.67=2/3, etc.

After you convert all the decimals to small-number ratios, multiply every fraction by a whole number to get whole-number-coefficients.

*** If you can't get small whole numbers, then something is fishy. Either the molecule is very complex, or there was an error made somewhere. For introductory chemistry problems, it should always work out to small whole numbers.
 

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