pervect said:
A quote from Wikipedia on
diffuse reflection might clarify the mechanism a bit:
So I know the process involves scattering, but I'm not sure of the details. Perhaps the question could use some refining - if so, the "reflection from a polished marble surface" as opposed to "reflection from a mirror" would be a specific inspirational example for why I asked the question. However, it's possible some other example would shed some insight on the issue and be easier to talk about and illustrate the physics more.
My technical background on the practical optical physics includes (ancient) techniques for producing diffuse reflectants, as for calibrations. Those relied on a crystalline powder -- likely TiO
2, though I don't recall. The crystals therefore perform as phase-randomizers: both tiny prisms and tiny mirrors, albeit mirrors that, as often as not, send their reflected photons further
into the powder, just because of the random orientation of the facets, rather than directly back out of it. (In certain ways, the mathematics is similar to diffuse scattering in particle physics or gravitation.)
Whether this is what marble effectively does or not, I do not know. But I do know that that powder was used for the very purpose of producing an easily reproducible, very diffuse (Lambertian) reflector. So I suggest that this may serve as a tractable model for your question.
The key for your question, I believe, is the word
random. If the material were either an absorber or a retro-reflector, momentum transfer would obviously be along the direction of incidence, rather than normal to the surface. It's the randomization that leaves the photon flux with no other preferred direction than the surface normal.
For single-facet reflectors, i.e., for random tiny mirrors, this involves an integration over either all the facet orientations or, equivalently, over the outbound photons' directions. The nice thing (for
perfect non-absorbers) is that, even for multiple reflections and for refraction, all the photons ultimately come out again, away from the surface. So you can perform the very same integration over the outbound photons' directions, without regard to their complicated paths in the middle. If the reflection is indeed Lambertian, the integration is symmetric with respect to the surface normal, so that's the direction of momentum transfer.
In fact, even if the surface only behaves as a linear combination of a Lambertian and a specular reflector, that can obviously hold as well, because it holds for both components. To take your example, perhaps that applies to polished marble.