Dirac Notation for Operators: Ambiguity in Expectation Values?

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Discussion Overview

The discussion revolves around the notation and interpretation of expectation values in quantum mechanics, particularly when dealing with linear operators that are not Hermitian. Participants explore how to express expectation values for operators like A² and A³, and whether the notation used can lead to ambiguity.

Discussion Character

  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • Some participants question the ambiguity in writing the expectation value of A² as < ψ | A² | ψ > versus < ψ | AA | ψ >, suggesting that the notation may not be clear.
  • One participant, Dan, asserts that if A is not Hermitian, then AA does not equal A†A, indicating that the two forms cannot be used interchangeably.
  • Another participant reiterates the method for calculating expectation values, emphasizing the need to specify the operator A before proceeding with calculations.
  • A different viewpoint suggests that for a pure state, the expectation value can be expressed as < Ψ | f(A) | Ψ >, regardless of whether the operator is self-adjoint, although this raises questions about the validity of calling it an "expectation value" if the operator cannot represent an observable.

Areas of Agreement / Disagreement

Participants express differing views on the clarity of the notation and the implications of using non-Hermitian operators. There is no consensus on whether the notation is ambiguous or on the appropriateness of calling certain expressions "expectation values."

Contextual Notes

Participants highlight that the discussion is limited by the lack of specification regarding the operator A, which affects the ability to resolve the ambiguity in notation and the interpretation of expectation values.

dyn
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Hi
If A is a linear operator but not Hermitian then the expectation value of A2 is written as < ψ | A2| ψ >. Now if i write A2 as AA then i have seen the expectation value written as < ψ | A+A| ψ > but if i only apply the operators to the ket , then could i not write it as < ψ | AA | ψ > ? In other words is the notation slightly ambiguous ?
Thanks
 
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dyn said:
Hi
If A is a linear operator but not Hermitian then the expectation value of A2 is written as < ψ | A2| ψ >. Now if i write A2 as AA then i have seen the expectation value written as < ψ | A+A| ψ > but if i only apply the operators to the ket , then could i not write it as < ψ | AA | ψ > ? In other words is the notation slightly ambiguous ?
Thanks
If A is not Hermitian, then ##AA \neq A^{\dagger} A##, so you can't write it that way.

-Dan
 
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I might be confusing myself here but if A is not Hermitian and A2 = AA and A3 = AAA then how do i write the expectation values of these 2 quantities ?
 
dyn said:
I might be confusing myself here but if A is not Hermitian and A2 = AA and A3 = AAA then how do i write the expectation values of these 2 quantities ?
The same way you did in the OP:
##\langle A^2 \rangle = \langle \psi \mid A^2 \mid \psi \rangle \equiv \langle \psi \mid AA \mid \psi \rangle##

You would have to calculate ##\mid \phi \rangle = A \mid \psi \rangle##, then ##\mid \zeta \rangle = A \mid \phi \rangle##, then finally ##\langle \psi \mid \zeta \rangle##.

That's as far as you can go until you specify what the operator A looks like.

-Dan
 
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topsquark said:
The same way you did in the OP:
##\langle A^2 \rangle = \langle \psi \mid A^2 \mid \psi \rangle \equiv \langle \psi \mid AA \mid \psi \rangle##

You would have to calculate ##\mid \phi \rangle = A \mid \psi \rangle##, then ##\mid \zeta \rangle = A \mid \phi \rangle##, then finally ##\langle \psi \mid \zeta \rangle##.

That's as far as you can go until you specify what the operator A looks like.

-Dan
Alternatively, you can calculate
$$
\begin{align*}
\ket{\phi} &= A \ket{\psi} \\
\ket{\chi} &= A^\dagger \ket{\psi} \\
\braket{\psi | A^2 | \psi} &= \braket{\chi| \phi}
\end{align*}
$$
 
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dyn said:
I might be confusing myself here but if A is not Hermitian and A2 = AA and A3 = AAA then how do i write the expectation values of these 2 quantities ?
For a pure state, represented by a normalized vector ##|\Psi \rangle## expectation value is
$$\langle f(\hat{A}) = \langle \Psi|f(\hat{A}) \Psi \rangle=\langle f(\hat{A})^{\dagger} \Psi|\Psi \rangle,$$
for an arbitrary function ##f(\hat{A})##. It doesn't matter whether the operator is self-adjoint or not for the identity of the two expressions. Of course, such an operator cannot represent an observable to begin with, and you might argue that it doesn't make sense to call this expression an "expectation value" in the first place.
 
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