Do Operators Have Units?

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Homework Help Overview

The discussion revolves around the units associated with operators in quantum mechanics, specifically the Hamiltonian. Participants are exploring whether operators have units, and how this relates to the wavefunction and physical quantities derived from them.

Discussion Character

  • Conceptual clarification, Assumption checking, Mixed

Approaches and Questions Raised

  • Participants are debating the dimensionality of the wavefunction and operators, questioning whether the Hamiltonian and other operators possess units. Some suggest that the wavefunction must have units to maintain dimensional consistency when applied to operators.

Discussion Status

There is an active exchange of ideas, with some participants affirming that operators do have units and referencing dimensional analysis in quantum mechanics. Others are clarifying misconceptions about the wavefunction's dimensionality, indicating a productive exploration of the topic.

Contextual Notes

Some participants mention specific expressions and relationships, such as Schrödinger's equation, to support their arguments. There is a recognition of the complexity involved in defining units for abstract mathematical constructs in quantum mechanics.

Niles
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Homework Statement


Hi all.

The title says it all: Say we have an operator - e.g. the Hamiltonian. Does this have units? I.e. does the Hamiltonian have units of Joules or nothing?

Personally I think it is nothing, since it is an operator, but I need confirmation.
 
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When you "apply" the operator to a wavefunction you "get" (some) energy . If the operator has no units then the wavefunction must have units of energy. But if you apply another operator to the same function you'll get another physical quantity... so the wave function cannot have units... the operator must came with the units "in it" :smile:

You don't need this "deduction" actually. Just look at the expression for Hamiltonian for example. It has Plank's constant and mass and length...all these have units
 
The wavefunction \psi(x) is NOT dimensionless, it does have units. In 1-D, when you integrate the absolute value squared of \psi you get 1: so, the dimension of the wavefunction must be 1/sqrt[length]. In 3-D, it similarly must have units of 1/[length]^(3/2).

Operators have units indeed. The momentum operator has units of momentum, etc. etc.
 
nasu said:
so the wave function cannot have units...
You are right, this statement is not true and it does not follow from the previous arguments.
Thank you.
 
The wave function only has units when it is expanded into a basis; \psi(x)=\left<x | \psi \right> has the units given by Borgwai, but the abstract wave function |\psi \rangle is generally treated as unitless.
 
gabbagabbahey said:
The wave function only has units when it is expanded into a basis; \psi(x)=\left<x | \psi \right> has the units given by Borgwai, but the abstract wave function |\psi \rangle is generally treated as unitless.

I'd refer to the ket |\psi \rangle as a state vector, not a wave function (just semantics).

But indeed, |\psi \rangle can be viewed as dimensionless, whereas |x \rangle has the dimension of [length]^(-1/2). This is the natural choice. I don't think there's a necessity of choosing the dual of a ket to have the same dimension as the ket itself: expressions whose dimension is clear always seem to contain both a ket and a bra (I'll be happy to see if someone knows a counter example!).
 
borgwal said:
The wavefunction \psi(x) is NOT dimensionless, it does have units. In 1-D, when you integrate the absolute value squared of \psi you get 1: so, the dimension of the wavefunction must be 1/sqrt[length]. In 3-D, it similarly must have units of 1/[length]^(3/2).

Operators have units indeed. The momentum operator has units of momentum, etc. etc.

Thanks borgwal

Another way to realize this (I just thought about this) is to look at Schrödingers time-independent equation: H \psi = E \psi.
 
Yes, I think that's what nasu meant also: the units of H follow from H \psi=E\psi.
 
Niles said:
Say we have an operator - e.g. the Hamiltonian. Does this have units?
As others have noted, of course they do. Even quantum mechanics is subject to dimensional analysis and had dang well be dimensionally correct. If we weren't careful about units, we physicists would be little different from (shudder) mathematicians. (D H quickly beats a hasty retreat to don a flame-retardant asbestos suit)
 
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<br /> \sqrt\{\f(x)}= \sqrt\{\g(x)}<br />
 

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