Effective mass of electrons in metals

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Discussion Overview

The discussion revolves around the concept of effective mass of electrons in metals and semiconductors, exploring its derivation, implications, and applications beyond heat capacity. Participants seek to understand the broader significance of effective mass in solid-state physics.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • One participant notes that the literature primarily connects effective mass to the heat capacity of metals but suggests its relevance extends further.
  • Another participant mentions the relationship between effective mass and mobility in semiconductors, referencing external sources for further reading.
  • A different participant emphasizes the understanding of effective mass in Fermi liquids through fermionic renormalization methods, citing specific research papers.
  • One participant describes effective mass as related to the curvature of the electronic dispersion relation, providing equations for both free electrons and electrons in a crystalline solid.
  • This participant expresses confusion regarding why effective mass can be lower than the free electron mass in semiconductors, questioning the physical implications of this phenomenon on electron behavior under an electric field.

Areas of Agreement / Disagreement

Participants do not appear to reach a consensus on the implications of effective mass, with ongoing questions and differing perspectives on its physical interpretation and applications.

Contextual Notes

There are unresolved questions regarding the physical mechanisms that lead to variations in effective mass, particularly in semiconductors, and the discussion reflects a range of assumptions about the underlying physics.

joel.martens
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The literature i have on the origins / need for an effective mass of electrons seems only to relate it to the explanation of heat capacity of metals but it seems like the concept has applications far beyond this. Can someone pls provide a more general summary of its derivation and applications?
Cheers.
 
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Effective mass of holes and electrons in semiconductors is closely related to mobility. See
http://en.wikipedia.org/wiki/Effective_mass_(solid-state_physics )
 
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The cleanest understanding of effective mass in Fermi liquids comes from a solid understanding of fermionic renormalisation methods. See any number of papers by Shankar on the topic.
 
I think of effective mass as a curvature of the electronic dispersion relation. I.e. for a free electron:
E = hbar^2 k^2 / 2m

where m is the mass of free electron.

Now, in a crystalline solid, where electronic band diagram applies, any band (near a symmetry point) can be represented as parabolic in k space, with its own curvature, i.e.:

E = hbar^2 k^2 / 2m*

where m* is the 'renormalized' mass of an particle in band (electron or a hole).

What is puzzling to me is why in for example semiconductors the effective mass is lower than the free electron mass? If I apply an external electric field, these electrons will reach steady state velocity larger than the free ones... what is physically happening that electron acts as if its inertia is lowered?
 

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