Efficiency of Carnot Engine Question

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SUMMARY

The discussion focuses on deriving the efficiency of a Carnot engine operating between two thermal reservoirs at temperatures T1 and T2, as outlined in "Equilibrium Statistical Physics" by Plischke and Bergerson. The efficiency formula is established as η = 1 - (T2/T1), where T1 > T2. The solution involves applying the first law of thermodynamics and the ideal gas law, with specific calculations for heat transfer during isothermal and adiabatic processes. The user successfully simplifies the efficiency equation using the relationships between volumes and temperatures in adiabatic processes.

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  • Understanding of the first law of thermodynamics
  • Familiarity with the ideal gas law (PV = Nk_BT)
  • Knowledge of isothermal and adiabatic processes
  • Concept of efficiency in thermodynamic cycles
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linford86
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Homework Statement



This is from "Equilibrium Statistical Physics" by Plischke and Bergerson, problem 1.1:

"Consider a Carnot engine working between reservoirs at temperatures T1 and T2. The working substance is an ideal gas obeying the equation of state [ PV=Nk_BT ], which may be taken to be a definition of a temperature scale. Show explicitly that the the efficiency of the cycle is given by

\eta=1-\frac{T_2}{T_1}

where T_1>T_2.

Homework Equations



The first law of thermodynamics, the ideal gas law, and a few other things. I'll introduce these in my partial solution; I hope that's not inappropriate.

The Attempt at a Solution



Well, I began by noting that the efficiency is defined as \eta=\frac{W}{Q_1}. We also know that W=Q_1+Q_2, using the convention that heat leaving the system is negative. For the sake of reference, I will define that the Carnot engine moves through points A, B, C, and D, and that AB is isothermal at temperature T_1, BC is adiabatic, CD is isothermal at temperature T_2, and DA is adiabatic. For the process from A to B, since it is isothermal, the internal energy does not change. By the first law of thermodynamics, we have that:

dU=0=\bar{d}Q-\bar{d}W and, thus, \bar{d}Q=\bar{d}W

Next, we have that \int_A^B \! dQ=\int_A^B P \, dV=Nk_BT\ln(\frac{V_B}{V_A}. Likewise, Q_2=Nk_BT\ln(\frac{V_D}{V_C}). Simplifying the equation for \eta, we have:

\eta=1+\frac{\ln(\frac{V_D}{V_C}}{\ln(\frac{V_D}{V_C}}

I understand that, for an adiabatic process, TV^\gamma=(constant) and that \gamma=\frac{C_D}{C_V}, but I have no idea how to use this information to further reduce \eta to the desired result --

\eta=1+\frac{T_2}{T_1}
 
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From adiabatic process (BC and DA), we have:

<br /> T_{2} V_{b} ^\gamma ^- ^1 = T_{1} V_{c} ^\gamma ^- ^1<br />

<br /> T_{2} V_{a} ^\gamma ^- ^1 = T_{1} V_{d} ^\gamma ^- ^1<br />

From 2 eq, we shall get:

<br /> \frac{V_{b}}{V_{a}} = \frac{V_{c}}{V_{d}}<br />

Plug it to efficiency to get a result.
 
Ha, that's so obvious! Thanks!

How do I mark this thread as "Solved"? I tried looking under "Thread Tools" but I didn't see an option for doing that...
 

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