Eigen Value and Eigen Function

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The discussion centers on the definitions and significance of eigenfunctions and eigenvalues in quantum mechanics, specifically in the context of the infinite square well. The eigen equation Aψ = λψ illustrates how operators relate to eigenfunctions and eigenvalues, with ψ representing the wavefunction and λ the energy eigenvalue. The analogy to linear algebra is emphasized, where eigenvectors and eigenvalues are defined similarly. The Hamiltonian operator is identified as the key operator in the time-independent Schrödinger equation, which is an eigenvalue problem. Understanding these concepts is crucial for solving quantum mechanical systems and their associated boundary conditions.
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I know that the eigen equation is given by A\psi =\lambda\psi where A is an operator and \psi is an eigen function and \lambda is an eigen value.
For the particle in an infinite square well of width L the wavefunction is given by \psi (x)=\sqrt{\frac{2}{L}}sin(\frac{n\pi x}{L}) and the energy is given by E=\frac{n^2h^2}{8ml^2}
I want to know why \psi is called eigen function and E is called the eigen value.
 
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From German eigen, meaning "distinct", "particular", "[one's] own".

It comes by analogy to linear algebra. If a vector \vec{v} is such that when you multiply a matrix A, by it, you get back the same matrix multiplied by some scalar (lambda):
\mathbf{A}\vec{v} = \lambda\mathbf{A}
Then \vec{v} is an eigenvector of A, and \lambda the corresponding eigenvalue. Any linear algebra textbook will tell you all about it.

This concept can be generalized to linear operators (matrix multiplication being a linear operation). For a linear operator \hat{O}, and a function f, if:
\hat{O}f = \lambda f

Then f is an eigenfunction of \hat{O}, and \lambda is again the corresponding eigenvalue. If you have a given operator and some boundary conditions, and wish to find the eigenfunctions and eigenvalues for it, then that's called an "eigenvalue problem".

For instance, the differential operator \hat{D}^n = \frac{d^n}{d x^n} is a linear operator.
So differential equations, such as \frac{df}{d x} - \lambda f(x) = 0 are eigenvalue problems.
 
hi roshan2004! :smile:

(have a psi: ψ and a lambda: λ and a pi: π and a square-root: √ and a curly d: ∂ :wink:)

your wavefunction should also have an eiωt factor

the (energy) operator A is ih∂/∂t (where I'm writing h for h-bar = h/2π),

so the (energy) eigenvalue is hω

(which just happens to be h(nπ/L)2/2m = h2n2/8mL2

see http://en.wikipedia.org/wiki/Square_well" :wink:)​
 
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Thanks, but in this case I couldnot find operator here, which is the operator in this case?
 
roshan2004 said:
Thanks, but in this case I couldnot find operator here, which is the operator in this case?

The Hamiltonian. The time-independent Schrödinger equation is simply the eigenvalue problem for the Hamiltonian.
Also, since V = 0 and you only have one dimension in the infinite square well, the Hamiltonian in that case is just the second-order differential operator (multiplied by -\hbar/2m)
 
Insights auto threads is broken atm, so I'm manually creating these for new Insight articles. Towards the end of the first lecture for the Qiskit Global Summer School 2025, Foundations of Quantum Mechanics, Olivia Lanes (Global Lead, Content and Education IBM) stated... Source: https://www.physicsforums.com/insights/quantum-entanglement-is-a-kinematic-fact-not-a-dynamical-effect/ by @RUTA

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