Electrochemistry and cell electroplating

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SUMMARY

The discussion focuses on the electroplating process involving a zinc cathode and an inert anode in a copper ion solution. When current is applied, copper ions undergo reduction at the cathode, while oxidation occurs at the anode, typically involving water electrolysis. The reactions are separate but must balance each other, with the potential of the cell determined by the specific electrochemical conditions present. The conversation emphasizes the importance of understanding both half-reactions in electrochemical cells.

PREREQUISITES
  • Basic understanding of electrochemistry principles
  • Knowledge of oxidation-reduction (redox) reactions
  • Familiarity with electroplating techniques
  • Understanding of cell potential calculations
NEXT STEPS
  • Study the Nernst equation for calculating cell potential
  • Explore the electrolysis of water and its role in electrochemical cells
  • Research the specifics of copper ion reduction and zinc oxidation reactions
  • Investigate different anode materials and their effects on electroplating efficiency
USEFUL FOR

Chemistry students, electrochemists, and professionals involved in electroplating processes will benefit from this discussion.

dec123
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Hello, I have a question in regards to electroplating. If i have a cell with let's say a zinc cathode and an inert anode in a solution of copper ions, and I turn on the current, what reaction will counter the reduction of copper ions to balance the electronegativity and what will be the potential of the cell?
 
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Hint: if there is nothing else to react and potential is high enough, there is always solvent present.
 
Borek said:
Hint: if there is nothing else to react and potential is high enough, there is always solvent present.
Ok, but the electrolysis of water is a reaction that balances itself, if there is already reduction of metal on the cathode, there can be only another oxidation which balances that reduction, is that not correct? If so, what is the exact reaction and what cathions are left in the water?
 
Is this a homework question?
 
dec123 said:
Ok, but the electrolysis of water is a reaction that balances itself

No, it is a sum of two separate processes, one occurring on the anode, the other on the cathode. They don't have to happen both at the same time.
 

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