Electrochemistry pH in solution cell

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SUMMARY

The discussion centers on the misunderstanding of pH assumptions in electrochemistry, specifically regarding the standard hydrogen electrode (SHE). The participant questions why pH is not assumed to be 0, as the problem implies the use of SHE, which typically involves a 1M H+ concentration. However, the problem statement specifies 1 atm, likely referring to hydrogen gas pressure rather than H+ concentration. This distinction is crucial for accurate electrochemical calculations.

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  • Understanding of electrochemical cells and their components
  • Knowledge of pH scale and its implications in solutions
  • Familiarity with the standard hydrogen electrode (SHE) concept
  • Basic principles of gas laws and their relation to concentration
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Chemistry students, electrochemists, and educators seeking clarity on pH assumptions in electrochemical systems.

yolo123
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Hello Forum :),

Please find attached my problem. The solutions is also there. BUT, I do not understand why my teacher does not simply assume pH=0. It seems as though we are using the standard hydrogen electrode (ie 1M H+ in solution!).
 

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Question never says "standard" hydrogen electrode. It also never says 1M H+, it says 1 atm - which is most likely meant to be 1 atm of H2.
 
Got it!
 

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