Electrolysis of water(ion and electrode)

Click For Summary

Discussion Overview

The discussion revolves around the electrolysis of water, specifically focusing on the roles of ions and electrodes. Participants explore the mechanisms of ion attraction to electrodes, the nature of electric fields generated during electrolysis, and the flow of electrons and ions within the electrolyte.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • One participant questions why positive ions are attracted to the negative electrode and what kind of force is emitted by the electrodes during electrolysis.
  • Another participant clarifies that the force attracting ions is electric, and that an electrode with an electron deficiency becomes positively charged, attracting anions.
  • There is a discussion about how the flow of electrons creates an electric field, with some participants expressing confusion about why one electrode is positive and the other negative despite both having electrons.
  • It is proposed that during electrolysis, one electrode loses electrons and becomes positively charged, while the other gains electrons and becomes negatively charged, leading to the movement of ions in the electrolyte.
  • One participant explains that in a circuit, positive ions cannot move in solid conductors, but can move in electrolytes, allowing for both electron and ion flow.
  • There is a question about whether more electrons gather at the negative electrode, which is affirmed by another participant who describes the negative electrode as the source of electrons for positive ions.

Areas of Agreement / Disagreement

Participants express varying levels of understanding and clarity regarding the concepts discussed. While some points are clarified, there remains uncertainty about the relationship between electron flow and electric fields, as well as the specific mechanics of ion movement in electrolytes.

Contextual Notes

Some participants express confusion over the terminology and concepts, indicating a need for clearer explanations. The discussion includes assumptions about the behavior of electrons and ions that may not be universally agreed upon.

Who May Find This Useful

This discussion may be useful for students and individuals interested in electrolysis, electrical circuits, and the behavior of ions and electrons in different mediums.

kevin_tee
Messages
80
Reaction score
2
I'm new to this forum, I am studying in grade 9 and I am working on my electrolysis project but I had trouble understanding about ion and electrode (this is not my homework, I just don't understand) why does positive ion attract to negative electrode, I know that positive should attract negative, but what king of force does the electrode emitting, because electrolysis is just adding some current to the electrode, so it is just a flow of electrons, negative is emitting electrons and positive is taking electrons so actually both electrode had an electrons. Why is positive ion is flowing against the flowing of electrons. If the electrode is emitting any kind of force field what is happening in side the electrode? Thank for every comments.:smile:
 
Chemistry news on Phys.org
I'm having a hard time understanding your question. Can you try to formulate it in a clearer fashion? Anyway, the force involved in attracting ions to electrodes is always electric. If an electrode has an electron defficiency, it will be positively charged and hence attract anions. The opposite is also true.
 
so the force attracting ions is electric field? Why does flowing of electron create an electric field?
I know that electron emit an electric field, but both electrode has electron so why one end is positive and another end is negative?
 
Last edited:
kevin_tee said:
so the force attracting ions is electric field? Why does flowing of electron create an electric field?
I know that electron emit an electric field, but both electrode has electron so why one end is positive and another end is negative?

Well, electrons are flowing from one electrode to the other, so one of them is going to have a net defficiency of electrons and a surplus of positive charges (from hydrogen I think). The other electrode is going to receive electrons and thus have a surplus of electrons (which leads to the formations of hyrdoxy anions, if I'm not mistaken) and therefore have a negative total charge.

In every electrode there are atoms, which have both electrons (negative) and protons (positive). If you take electrons away from the atoms in the first electrode and give them to the atoms in the second electrode, then the atoms in the first electrode are going to become postively charged and vice-versa.
 
kevin_tee said:
I'm new to this forum, I am studying in grade 9 and I am working on my electrolysis project but I had trouble understanding about ion and electrode (this is not my homework, I just don't understand) why does positive ion attract to negative electrode, I know that positive should attract negative, but what king of force does the electrode emitting, because electrolysis is just adding some current to the electrode, so it is just a flow of electrons, negative is emitting electrons and positive is taking electrons so actually both electrode had an electrons. Why is positive ion is flowing against the flowing of electrons. If the electrode is emitting any kind of force field what is happening in side the electrode? Thank for every comments.:smile:

When you start your electrolysis you apply a voltage to your electrodes. This causes one of them to be positively charged and one to be negatively charged. If there were no electrolyte in between them then no current would flow and nothing would happen. However because the electrolyte conducts electricity we get a flow of current between the two electrodes. The electrolyte is completing the circuit between the two electrodes, just like normal water can do to a normal circuit or electronic device. (Which generally causes a short to occur)

Now, in a normal circuit made of wires, the positive ions cannot move as they are the nuclei of the atoms in the metal and are stuck in place. Thus only the electrons move around. However in an electrolyte positive ions CAN move because the electrolyte is a liquid, not a solid. So you can have electrons moving from the cathode(-) to the anode(+), and ions moving from the anode to the cathode.

kevin_tee said:
so the force attracting ions is electric field? Why does flowing of electron create an electric field?
I know that electron emit an electric field, but both electrode has electron so why one end is positive and another end is negative?

The flowing of electrons doesn't create an electric field. The field is caused by your power source for the circuit creating a voltage, which is a difference in electrical potential between two spots. If you connect the terminals of a battery together a current will flow because one terminal is + and the other is - and will send electrons through your circuit from the - terminal to the + terminal. The way this voltage is generated is actually the reverse of electrolysis. (Just for a battery, not for generators and other ways of producing electrical power)
 
Does it mean that on the negative electrode side there are more electron gathering there?
 
kevin_tee said:
Does it mean that on the negative electrode side there are more electron gathering there?

The negative electrode acts as the source of electrons to give to the positive ions. It is where they electrons enter the electrolyte at. The positive electrode is where the electrons leave the electrolyte and enter the rest of the circuit. The total number of electrons in the electrons remains the same because while you have some entering from the negative electrode you have an equal number leaving at the positive electrode.
 

Similar threads

Replies
4
Views
2K
Replies
3
Views
2K
Replies
3
Views
2K
  • · Replies 3 ·
Replies
3
Views
2K
  • · Replies 5 ·
Replies
5
Views
2K
  • · Replies 2 ·
Replies
2
Views
2K
  • · Replies 4 ·
Replies
4
Views
2K
  • · Replies 6 ·
Replies
6
Views
3K
  • · Replies 23 ·
Replies
23
Views
6K
  • · Replies 9 ·
Replies
9
Views
4K