Electron and wavelength problem

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Discussion Overview

The discussion revolves around a homework problem involving the emission of a wavelength by an electron transitioning between energy levels in an atom. Participants are attempting to determine the final energy level based on the given wavelength of 410.2 nm, using the Rydberg formula for hydrogen-like atoms.

Discussion Character

  • Homework-related
  • Mathematical reasoning
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant presents the Rydberg formula and attempts to calculate the final energy level but arrives at an incorrect value, questioning their approach.
  • Another participant points out that the variables N and n in the formula represent the lower and upper energy levels, respectively, and suggests checking the units used in the calculations.
  • There is a discussion about the correct handling of units, with one participant suggesting that calculations might be simplified using powers of ten to avoid errors.
  • Participants debate the addition of fractions, with one stating that the property used for logarithms does not apply to the addition of inverses, which is relevant to their calculations.
  • One participant expresses confusion about their results, indicating a value of 0.66666, and another participant requests to see the calculations to verify the results.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the correct calculation method or the final energy level. There are multiple competing views on how to properly apply the Rydberg formula and handle the mathematical operations involved.

Contextual Notes

There are unresolved issues regarding the proper application of the Rydberg formula, unit conversions, and the addition of fractions in the context of the problem. Participants express uncertainty about their calculations and the correct interpretation of the formula.

David112234
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Homework Statement


Electron on n=6 level emits wavelength of 410.2nm.
What energy level does it move too?

Homework Equations


1/L = R ( 1/N^2 - 1/n^2)
where N is initial and n final
R=1.096779*10^7 m

The Attempt at a Solution


1/410.2 = 10967790 (1/36 - 1/n^2)
1/4498975152 = (1/36 - 1/n^2)
-1/36 -1/36
4498975152 =n^2
sqrt
n=67074...
this number is wrong, it is not an energy level, and not one of the answers, what did I do wrong?
 
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David112234 said:
1/L = R ( 1/N^2 - 1/n^2)
where N is initial and n final
Careful here. N is the lower level and n is the upper level, not necessarily initial and final.

Put the units in your equation, you will see where it went wrong.
 
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DrClaude said:
Careful here. N is the lower level and n is the upper level, not necessarily initial and final.

Put the units in your equation, you will see where it went wrong.
alright,
R is in m^-1
and L is in nm,

so it will be .0000004102m*10967760m^-1 = .449897515 m/m
Now I add 36 and take the sqrt, which gives me a number slightly larger than 6, which still is not correct. Did I miss other units?
 
David112234 said:
so it will be .0000004102m*10967760m^-1 = .449897515 m/m
Almost. I think it is simpler to make calculation using powers of 10 (less chance of an error):
410.2×10-9 m × 1.096779×107 m-1 = ?

David112234 said:
Now I add 36 and take the sqrt
You can't do that,
$$
\frac{1}{a} + \frac{1}{b} \neq \frac{1}{a+b}
$$
You need to add 1/36 to 1 over the number you will get for λ×R.
 
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DrClaude said:
Almost. I think it is simpler to make calculation using powers of 10 (less chance of an error):
410.2×10-9 m × 1.096779×107 m-1 = ?You can't do that,
$$
\frac{1}{a} + \frac{1}{b} \neq \frac{1}{a+b}
$$
You need to add 1/36 to 1 over the number you will get for λ×R.

I thought since all the terms were under 1 that I could just solve the denominators, like this property

X(2x+5) = x14
2x+5= 14

also, how do you display fractions on this forum like you did?
 
David112234 said:
I thought since all the terms were under 1 that I could just solve the denominators, like this property

X(2x+5) = x14
2x+5= 14
That makes use of the properties of the logarithm
$$
\begin{align*}
x^a &= x^b \\
\log(x^a) &= \log(x^b) \\
a \log(x) &= b \log(x) \\
a &= b
\end{align*}
$$
It doesn't work for ##a^{-1} + b^{-1}##.

David112234 said:
also, how do you display fractions on this forum like you did?
I used the Latex capabilities of PF. See https://www.physicsforums.com/help/latexhelp/ for more info.
 
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DrClaude said:
That makes use of the properties of the logarithm
$$
\begin{align*}
x^a &= x^b \\
\log(x^a) &= \log(x^b) \\
a \log(x) &= b \log(x) \\
a &= b
\end{align*}
$$
It doesn't work for ##a^{-1} + b^{-1}##.I used the Latex capabilities of PF. See https://www.physicsforums.com/help/latexhelp/ for more info.

Thank you. I did it all out and the value I got it .66666, which still does not seem right
 
David112234 said:
I did it all out and the value I got it .66666, which still does not seem right
Indeed. I get a nice value. Could you show your calculation?
 

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