rewebster: Once again, this problem was worked to death in the 1930s. Time dependent perturbation theory does an excellent job of describing the dynamics of atomic jumps, cf, Weisskopf and Wigner, Breit and Wigner (after WWII) Go back, whether in Google, or such classics as Condon and Shortley -- Theory of Atomic Spectra, and, if I recall correctly, see also Blatt and Weisskopf's book Theoretical Nuclear Physics;, Schwinger's volume of key QED papers, Quantum Electrodynamics, Dirac's QM book, Books by Jauch and Rohrlich, Schweber -- his old text, and more recent history of QED -- Wentzel,, Akheiser and Berestski and on and on and on.
Everything you want to know about this issue can be found in the literature.
If you want to pursue what you write below, then your best bet is probably the WKB method, which ties together QM and classical mechanics. (And, don't forget the Dirac Eq. for hydrogen).
In QM, as we know it now, there really is no "jump", as there was in the old quantum theory of Bohr and Sommerfeld. That's why it's important to study the time dependence of the radiation process, which shows a smooth transition from one state to another -- for electrons and other charged particles, and photons as well.
Check out the literature. What you want to know has been there a long, long time.
Regards,
Reilly Atkinson
rewebster said:
On my question in 51 and in relation to the electron 'jump':
What I was moving toward was two possibilities.
The first, taking one given radius of the hydrogen atom and hypothetically taking it as the distance between shells (I haven't found anything on the measured distances between shells) in a Copernican based model, the time may be around 5 x 10 to the minus 21 sec. for the electron (at LS) to jump. Would that be considered instantaneous? Even if the speed of the jump occurred a million times slower, it would still be to the minus 15 sec. (if my math is right ) ---Still fast.
The other model could be of a tangentially based orbit of the electron (Gryziński M.)--of which, in this case, the electron, when, at 'some' time during its cycle (orbit, tangential or distal?), would lose the photon. The crossing point to another shell could very easily be at the tangential proximity to the nucleus with a much shorter distance to make the 'jump'. In this case, the 'jump' may be of even a less time difference than the first scenario (even more instantaneous).
Anyone have any other thoughts?---(I hope that this post isn't considered overly-speculative.)