Energy eigenvalue for particle in a box

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SUMMARY

The discussion focuses on calculating the energy eigenvalue for a particle in an infinite square well, specifically how to determine the probability of measuring a given energy eigenvalue from a provided wavefunction. The wavefunction can be expressed as a linear combination of energy eigenfunctions, represented as ψ = a_1 ψ_1 + a_2 ψ_2 + a_3 ψ_3 + .... The coefficients a_k correspond to the probabilities of measuring the respective energy eigenvalues E_k. The orthogonality and normalization of the eigenfunctions are crucial for deriving these coefficients.

PREREQUISITES
  • Understanding of quantum mechanics principles, specifically wavefunctions and energy eigenvalues.
  • Familiarity with the concept of infinite square wells in quantum mechanics.
  • Knowledge of orthogonality and normalization of functions in quantum mechanics.
  • Ability to perform integrals involving complex functions.
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  • Study the mathematical formulation of the infinite square well potential in quantum mechanics.
  • Learn about the orthogonality of quantum states and how it applies to energy eigenfunctions.
  • Explore methods for calculating coefficients in linear combinations of wavefunctions.
  • Investigate the implications of measurement in quantum mechanics, particularly regarding probabilities and expectation values.
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Students and professionals in physics, particularly those specializing in quantum mechanics, as well as educators looking to enhance their understanding of energy eigenvalues and wavefunction analysis.

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Hello all, I'm stuck on this question, and I would appericate if someone can tell me how to start cracking the problem.

I have a infinite square well, and is given a wavefunction that exist inside the well. The problem is to find the probability that a measurement of the energy will result in a certain given energy eigenvalue. Also I have to find the mean energy.


Thanks in advance.
 
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The wavefunction that you're given is not one of the eigenfunctions of the inifinite square well, right?

In general, any wave function that satisfies the boundary conditions for a physical situation (such as the infinite square well) can be written as a linear combination of the energy eigenfunctions:

[tex]\psi = a_1 \psi_1 + a_2 \psi_2 + a_3 \psi_3 + ...[/tex]

where [itex]\psi_1[/itex] has energy eigenvalue [itex]E_1[/itex], and [itex]a^*_1 a_1[/itex] gives the probability that the particle has energy [itex]E_1[/itex]. So your problem is to find out what the [itex]a_k[/itex] are, or at least some of them.

The energy eigenfunctions are orthogonal, which means that

[tex]\int {\psi^*_j \psi_k dx} = 0[/tex]

whenever [itex]j \ne k[/itex]. Suppose that the eigenfunctions are also normalized so that

[tex]\int {\psi^*_k \psi_k dx} = 1[/tex]

for any k. Take the first equation above and multiply through by (say) [itex]\psi^*_2[/itex]:

[tex]\psi^*_2 \psi = a_1 \psi^*_2 \psi_1 + a_2 \psi^*_2 \psi_2 + a_3 \psi^*_2 \psi_3 + ...[/tex]

Then integrate both sides. Look at what happens to the integrals on the right side, and you should see how to calculate [itex]a_2[/itex], and how to generalize this method to any value of k.
 

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