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If you are dealing with "real" rubber ballons you will find that a He filled balloon will relativly quickly (24hrs) sink, where a balloon made of mylar will float for days or even weeks. He is small enough that it will pass through the pores of a rubber ballloon, thus the loss of buoyancy. A similar balloon filled with H would loose bouancy even faster then He.
There is also the fun part of H, that is its love affair with O2.
There is also the fun part of H, that is its love affair with O2.