Fermi and Bose gas in statistical mechanics

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SUMMARY

This discussion focuses on the relationship between the approximations for the fugacity (z) and the thermal de Broglie wavelength (nλ^3) in the context of ideal Fermi and Bose gases as described in "Statistical Mechanics" by Pathria (3rd edition). It is established that the approximations for z and nλ^3 are not necessarily correlated. The Fermi-Dirac (FD) or Bose-Einstein (BE) function equals z only at low temperatures when z is significantly less than 1. At higher temperatures, z approaches 1, while the FD or BE function diverges from z and can differ from nλ^3.

PREREQUISITES
  • Understanding of Fermi-Dirac and Bose-Einstein statistics
  • Familiarity with the concept of fugacity in statistical mechanics
  • Knowledge of thermal de Broglie wavelength and its significance
  • Basic principles of ideal gas behavior
NEXT STEPS
  • Study the derivation of the Fermi-Dirac and Bose-Einstein distributions
  • Explore the implications of low versus high temperature behavior in quantum gases
  • Investigate the concept of fugacity in greater detail, particularly in relation to phase transitions
  • Learn about the ideal gas limit and its effects on quantum statistical mechanics
USEFUL FOR

Students and researchers in physics, particularly those specializing in statistical mechanics, quantum mechanics, and thermodynamics, will benefit from this discussion.

Sang-Hyeon Han
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In statistical mehcanics(pathria, 3rd edition), I have some questions for ideal fermi and bose gases. The textbook handles the approximation for z(=e^βµ) and nλ^3 (n=N/V, λ : thermal de Broglie wavelength). It considers the cases that z<<1, z~1, nλ^3~1,<<1,→0 and so on. In here, I am confused that these approximation for z and nλ^3 are correlated with ecah other or not?? In some approximation , FD(or BE) function is almost equal to z and z is equal to nλ^3! I am really confused. So could you explain that for me??
 
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The approximation for z and nλ^3 are not necessarily correlated with each other. The Fermi-Dirac (or Bose-Einstein) function is equal to z only at low temperatures, when z is much smaller than 1. At higher temperatures, when z is close to 1, the FD (or BE) function is not equal to z, and it can be different from nλ^3 too. For example, in the ideal gas limit, when nλ^3→0, the FD (or BE) function tends to a constant value, while z→1.
 

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