Ferrimagnetism vs ferromagnetism

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SUMMARY

This discussion focuses on the distinctions between ferrimagnetism and ferromagnetism, emphasizing that ferrimagnetic materials have unequal opposing magnetic moments, resulting in spontaneous magnetization. Key examples include ferrites and magnetic garnets, with magnetite (Fe3O4) being a historically significant ferrimagnet. The conversation also highlights the importance of measuring magnetic properties to differentiate between these two types of magnetism, particularly in materials with unknown proportions of Fe2+ and Fe3+ ions.

PREREQUISITES
  • Understanding of magnetic moments and sublattices
  • Familiarity with ferrimagnetic materials such as ferrites and magnetic garnets
  • Knowledge of iron oxides, specifically Fe2+ and Fe3+ ions
  • Basic principles of magnetism and its measurement techniques
NEXT STEPS
  • Research measurement techniques for magnetic properties, such as vibrating sample magnetometry (VSM)
  • Study the differences in magnetic behavior between ferrimagnetic and ferromagnetic materials
  • Explore the role of ion proportions in determining magnetic properties in iron oxides
  • Investigate the historical context of magnetite and its classification evolution in magnetism
USEFUL FOR

Students and researchers in physics, materials science professionals, and anyone interested in the properties and applications of magnetic materials.

username327
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Hello All,

I am trying to learn about the diffrerent types of magnetism and would like to know how we can tell the difference between ferri- and ferromagnetism? Are their any measurements which can distinguish unequivocally between the two types?

Thank you for any help
 
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From: http://en.wikipedia.org/wiki/Ferrimagnetism

In physics, a ferrimagnetic material is one in which the magnetic moments of the atoms on different sublattices are opposed, as in antiferromagnetism; however, in ferrimagnetic materials, the opposing moments are unequal and a spontaneous magnetization remains. This happens when the sublattices consist of different materials or ions (such as Fe2+ and Fe3+).

Ferrimagnetism is exhibited by ferrites and magnetic garnets. The oldest-known magnetic substance, magnetite (iron(II,III) oxide; Fe3O4), is a ferrimagnet; it was originally classified as a ferromagnet before Néel's discovery of ferrimagnetism and antiferromagnetism in 1948 [1].

Some ferrimagnetic materials are YIG (yttrium iron garnet) and ferrites composed of iron oxides and other elements such as aluminum, cobalt, nickel, manganese and zinc.
 
Hello pallidin,

Thanks for the quick reply.

Ok so let's assume we are talking about an Fe-oxide for which we don't have any knowledge of the proportions of Fe3+ and Fe2+ but we want to know which type of magnetism it exhibits. Is there a measurement of its magnetic properties we can make which will differentiate between ferri- and ferro? (I know that by implication ferri => some Fe2+)

Thanks
 
Last edited:
Thanks. Wish I had more knowledge on this subject.
Perhaps an expert can jump-in and elucidate.
 

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