Find the energy levels of a spin s = 3/2 particle

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SUMMARY

The discussion focuses on finding the energy levels of a spin \( s = \frac{3}{2} \) particle using the Hamiltonian \( \hat{H} = \frac{a_1}{\hbar^2}(\hat{S}^2 - \hat{S}_x^2 - \hat{S}_y^2) - \frac{a_2}{\hbar}\hat{S}_z \). The matrix representations for \( \hat{S}_z \) and \( \hat{S}^2 \) are provided, and the Hamiltonian is reformulated to \( \hat{H} = \frac{-1}{4}\begin{bmatrix} a_1 + 2a_2 & 0 \\ 0 & a_1 - 2a_2 \end{bmatrix} \). The next steps involve calculating the energy for each \( m_s \) value, specifically \( m_s = -\frac{3}{2}, -\frac{1}{2}, \frac{1}{2}, \frac{3}{2} \). The discussion also clarifies that the evaluation of \( m_j \) values typically follows a descending order.

PREREQUISITES
  • Understanding of quantum mechanics concepts, specifically spin systems.
  • Familiarity with Hamiltonians and their matrix representations.
  • Knowledge of the \( \hat{S}_z \) and \( \hat{S}^2 \) operators.
  • Ability to perform matrix multiplication and eigenvalue calculations.
NEXT STEPS
  • Learn how to calculate energy eigenvalues for spin systems using Hamiltonians.
  • Study the properties of angular momentum operators in quantum mechanics.
  • Explore the conventions for ordering quantum states and their implications in calculations.
  • Investigate the differences in Hamiltonian formulations for various spin values.
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Students and researchers in quantum mechanics, particularly those studying angular momentum and spin systems, as well as educators looking to clarify concepts related to Hamiltonians and energy levels of particles with non-integer spin values.

pondzo
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Homework Statement



Find the energy levels of a spin ##s=\frac{3}{2}## particle whose Hamiltonian is given by:

##\hat{H}=\frac{a_1}{\hbar^2}(\hat{S}^2-\hat{S}_x^2-\hat{S}_y^2)-\frac{a_2}{\hbar}\hat{S}_z## where ##a_1## and ##a_2## are constants.

Homework Equations



In the ##\hat{S}_z## basis ##\hat{S}_z## and ##\hat{S}^2## have the following matrix representations:

##\hat{S}_z=\frac{1}{2}\hbar\begin{bmatrix}1&&0\\0&&-1\end{bmatrix}##

##\hat{S}^2=\frac{3}{4}\hbar^2\begin{bmatrix}1&&0\\0&&1\end{bmatrix}##

The Attempt at a Solution



We can rewrite the Hamiltonian as follows:

##\hat{H}=\frac{a_1}{\hbar^2}(2\hat{S}_z^2-\hat{S}^2)-\frac{a_2}{\hbar}\hat{S}_z##

Subbing the matrices in the "relevant equations" I get the following matrix representation for the Hamiltonian:

##\hat{H}=\frac{-1}{4}\begin{bmatrix}a_1+2a_2&&0\\0&&a_1-2a_2\end{bmatrix}##

I'm not sure where to go from here... since ##s=\frac{3}{2}## then ##m_s=-\frac{3}{2},-\frac{1}{2},\frac{1}{2},\frac{3}{2}##. Is the next step to work out the energy for each of these ##m_s## values?
So find: ##\langle\frac{3}{2},-\frac{3}{2}|\hat{H}|\frac{3}{2},-\frac{3}{2}\rangle,\langle\frac{3}{2},-\frac{1}{2}|\hat{H}|\frac{3}{2},-\frac{1}{2}\rangle,\langle\frac{3}{2},\frac{1}{2}|\hat{H}|\frac{3}{2},\frac{1}{2}\rangle,\langle\frac{3}{2},\frac{3}{2}|\hat{H}|\frac{3}{2},\frac{3}{2}\rangle,##? If so, I am a little confused as to the vector forms of some of those bras and kets.. Help is appreciated!

(Oh and by the way, my Lecturer made a mistake when he said a particle with spin s = 3/2, but he said to do the question regardless)
 
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pondzo said:

Homework Equations



In the ##\hat{S}_z## basis ##\hat{S}_z## and ##\hat{S}^2## have the following matrix representations:

##\hat{S}_z=\frac{1}{2}\hbar\begin{bmatrix}1&&0\\0&&-1\end{bmatrix}##

##\hat{S}^2=\frac{3}{4}\hbar^2\begin{bmatrix}1&&0\\0&&1\end{bmatrix}##
Those relations hold only for spin one-half particles. You don't need matrix representation actually, just use the fact that ##S^2 = S_x^2 + S_y^2 + S_z^2## to modify the first three terms contained in the bracket in the Hamiltonian.
 
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Hi Blue leaf, I realized this after I made the post and I think I have the correct answer now.

I just have one question: Is there a convention as to which order you evaluate the different ##m_j## values when computing the matrix elements? Is it ascending or descending?
 
pondzo said:
I just have one question: Is there a convention as to which order you evaluate the different ##m_j## values when computing the matrix elements? Is it ascending or descending?
It is usually descending, just like for a spin-1/2 particle:
$$\hat{S}_z=\frac{1}{2}\hbar\begin{bmatrix}1&0\\0&-1\end{bmatrix}$$

spin-3/2:
$$\hat{S}_z=\frac{1}{2}\hbar\begin{bmatrix}3&0&0&0\\0&1&0&0\\0&0&-1&0\\0&0&0&-3 \end{bmatrix}$$
But it is always better to specify which convention is used.
 
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Ok thanks for the help!
 

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