What is Energy levels: Definition and 276 Discussions
A quantum mechanical system or particle that is bound—that is, confined spatially—can only take on certain discrete values of energy, called energy levels. This contrasts with classical particles, which can have any amount of energy. The term is commonly used for the energy levels of the electrons in atoms, ions, or molecules, which are bound by the electric field of the nucleus, but can also refer to energy levels of nuclei or vibrational or rotational energy levels in molecules. The energy spectrum of a system with such discrete energy levels is said to be quantized.
In chemistry and atomic physics, an electron shell, or principal energy level, may be thought of as the orbit of one or more electrons around an atom's nucleus. The closest shell to the nucleus is called the "1 shell" (also called "K shell"), followed by the "2 shell" (or "L shell"), then the "3 shell" (or "M shell"), and so on farther and farther from the nucleus. The shells correspond with the principal quantum numbers (n = 1, 2, 3, 4 ...) or are labeled alphabetically with letters used in the X-ray notation (K, L, M, N…).
Each shell can contain only a fixed number of electrons: The first shell can hold up to two electrons, the second shell can hold up to eight (2 + 6) electrons, the third shell can hold up to 18 (2 + 6 + 10) and so on. The general formula is that the nth shell can in principle hold up to 2(n2) electrons. Since electrons are electrically attracted to the nucleus, an atom's electrons will generally occupy outer shells only if the more inner shells have already been completely filled by other electrons. However, this is not a strict requirement: atoms may have two or even three incomplete outer shells. (See Madelung rule for more details.) For an explanation of why electrons exist in these shells see electron configuration.If the potential energy is set to zero at infinite distance from the atomic nucleus or molecule, the usual convention, then bound electron states have negative potential energy.
If an atom, ion, or molecule is at the lowest possible energy level, it and its electrons are said to be in the ground state. If it is at a higher energy level, it is said to be excited, or any electrons that have higher energy than the ground state are excited. If more than one quantum mechanical state is at the same energy, the energy levels are "degenerate". They are then called degenerate energy levels.
From the first equation, there are 5 constants, e, ##\pi##, ##\varepsilon_0##, ##n^2##, and 32. The only difference is m, where helium has around four times the mass of hydrogen. What I don't get is if there is a difference between the energy levels of the hydrogen and the ionized hellium? Also...
Hello! Im a freshman in college, taking pretty basic chem classes and Ive found myself in a deep dive regarding quantum physics. Im sure this is pretty simple and easy compared to everyone else on here but I feel like I keep getting oversimplified answers that just leave me with more...
We know that electrons bound to an atom can only absorb light with certain energies that match the energy difference between two energy levels or otherwise this implies electrons can exist in between energy levels. Then electrons will spiral into the nucleus due to the attractive forces between...
Hi guys,
Can you give me some feedback on whether my calculation is correct? I applied the formula below (Boltzmann Distribution) but I didn‘t know what to use for the variable z. I don‘t even know if I used the correct equation. Can you help me further?
The task is:
Consider a system of...
Is it a total energy of a vibrating molecule? So is it a sum of potential and kinetic energy? Or it is only a total energy of a vibrational motion of the molecule? Or is it only a potencial energy, when it is related to a dissociation curve? I am confused.
I find this very interesting. But it is above my head. Is there a simpler explanation/volume perhaps that I could get, consult?
https://www.sciencedirect.com/topics/earth-and-planetary-sciences/atomic-energy-levels
Hello! I have 2 levels of the same parity with energies ##E_1 < E_2##, and another level of opposite parity a distance ##E## from the ##E_2##. I also have that ##E_2 - E_1 << E##. I have a laser on resonance (I am trying to scan along the resonance and find it) with the transition from ##E_2##...
Hello !
My question is how the energy levels and sublevels that atoms are considered to have were obtained, and if these energy levels and sublevels were obtained as a result of the different spectroscopic analyzes of energy emission and absorption of atoms, or as it was concluded that atoms...
Hello! I am reading this paper and in deriving equations 6/7 and 11/12 they claim to use second oder time dependent perturbation theory (TDPT) in order to get the correction to the energy levels. Can someone point me towards some reading about that? In the QM textbooks I used, for TDPT they just...
Hello! This is quite a specific question, so if anyone knows the details I would really appreciate your help (@Twigg ?). I am trying to reproduce figure 1 from this paper (it's for the PV experiment performed on BaF). While I am getting quite close to it, the levels don't fully match (I am...
I am sure this is an elementary question; I'm just trying to clarify some points that were poorly explained to me years ago in secondary school. I know that a full answer would involve solving Schrödinger's equation etc., but keeping this on the level of valence electrons,...) I was confused by...
I determined the partition function of the particle A, B and C.
C should be the same as B.
I then considered the situation, where all particles are in the system at the same time, and drew a diagram of all possible arrangements:
The grey boxes are the different partitions, given that we...
My book says that emission spectra are produced when an electron in excited state jump from excited to lower energy states. It also states that solids and liquids produce continuous spectra and it depends upon temperature only (is this black body radiation?).
I know, Electrons around a nucleus...
In p.385 of Griffiths QM the vector potential ##\textbf{A} = \frac{\Phi}{2\pi r}\hat{\phi}## is chosen for the region outside a long solenoid. However, couldn't we also have chosen a vector potential that is a multiple of this, namely ##\textbf{A} = \alpha \frac{\Phi}{2\pi r} \hat{\phi}## where...
Hello! If I have 2 energy levels split by something of the order of 10 Hz (they can be connected by an electric dipole moment i.e. ##\Delta J = 0## and they have different parities), what would be the best way to measure this difference (even 10% error would be good, but the lower the error the...
Homework Statement:: Ionised atom, free electron, conduction band, donor energy level and acceptor energy level
Relevant Equations:: None
I have some confusion about the concept of some electronic bands and energy levels.
Beyond valance band, in a solid crystal lattice,
For an atom, can...
In Example 41.5, they are implying that, for a hydrogen atom, if the orbital quantum number ##l## goes down the electron will lose energy. However, they said nothing about the principal quantum number ##n## going down, so there should be no loss in energy. As far as this book has presented, the...
So I read that Bohr's atom has discrete energy levels that an Electron can orbit at and that each level has n amount of sublevels (if n = 2 then there are 2 sublevels). Does the sublevel that the Electron is in have to do with it's mass? Does an electron in energy level l and sublevel d have...
Thank you for reading :bow:
Section 1
To find the energy states of the particle, we define the wave function over three discrete domains defined by the sets ##\left\{x<-L\right\}##, ##\left\{-L<x<L\right\}##, and ##\left\{L<x\right\}##. The time independent Schrodinder equation is...
Many of you would have heard about physical energy levels. Like maintaining the physical energy throughout the day so that you do not get tired. People recommend exercising, meditating etc etc.
But I found out that my mental energy drains at a very rapid rate. I wake up with full energy but...
Hello
Can some one explain how you work out the combinations of quantum numbers for infinite wells in higher dimensions?
For example if i have an energy level $$E_4$$ In a 2D well, then for quantum numbers does this mean the combinations allowed must be:
$$4^2 + 1^2$$
$$1^2 + 4^2$$
So then...
Given a particle in a 1D box with a finite number of states ##m##, is the probability a particle is in a certain state ##n## equal to the energy of that state divided by the sum of energies of all states? In other words, given $$ E_n = \dfrac{n^{2}h^{2}}{8mL^{2}}$$ is $$P_n=...
Electron can move from lower energy level to higher energy level when it absorbs energy equal to the difference between the energy levels based on equation: ##hf = \Delta E##
If the incident photon has lower energy compared to ##\Delta E##, then electron won't move to higher energy level. But...
I know that there is a boundary condition at ##x=0## where the wave function becomes zero however why are the allowed energy levels odd i.e. ##n=1, 3, 5 ..##
1. The 4th line from the left, being the aqua blue line, corresponds to a wavelength of 486 nm, as blue light has a wavelength in the range 450-495 nm.
2. This is where I am having the most difficulty, I have tried to answer the question comprehensively but I am not satisfied with my answer.
In...
I often read of photons manifesting different levels of energy. I know that energy increases as wavelength decreases and frequency increases. Are there other ways particles gain or lose energy? As water boils heat energy is transferred to the water causing water molecules to move faster and to...
I'm trying to understand the detailed concept of why the density of states formula is accurate enough to calculate the number of quantum states of an energy level, including degeneracy, within a small energy interval of ##dE##.
The discrete energie levels are calculated by
$$E = \frac{h^2 \cdot...
Hi,
The ionization energy is defined as the minimum amount of energy required to remove the most loosely bound electron, the valence electron, of an isolated neutral gaseous atom.
Our physics teacher also told us while explaining this concept in the context of energy levels, that it is equal...
From what I read I see that for example a radioactive nucleus is a nucleus in an excited state and when it transitions back to it's stable state (changes from one element to another due to radioactive decay) one of the ways this happens is that the nucleus emits a energetic photon with a...
I'm considering a hydrogen atom placed in an infinite potential on one side of the nucleus, i.e. ##V(x) = +\infty## for ##x < 0##. I require the wavefunctions to be odd in order to satisfy the boundry condition at ##x=0##. By parity of the spherical harmonics only states with ##l## odd are...
I would like to get some information on this topic. It is not discussed in many places, so if any members here know about it, i would be interested in a brief explanation. Or any books or online documents where it is discussed.
D is the "invariant propagation function" or the "propagator". I...
Hello, I'm doing some refreshers before going back to school. Stat mech is my shakiest and I'd appreciate some help on this problem.
I know that for a single particle, the partition function will be $$Z = 1 + 2e^{-\beta\Delta} + 2e^{-4\beta\Delta}$$ and so its internal energy is $$\frac{1}{Z}...
Summary: Does an atom in an excited state have a higher mass than when in its ground state?
Summary: Does an atom in an excited state have a higher mass than when in its ground state?
Does an atom in an excited state have a higher mass than when in its ground state?
I found one answer somewhere else in the internet, It specified there that atoms cannot have rotational and vibrational energies since they don't have a point on them that will allow the atom to be rotated or vibrated. However , that answer did not suffice so I ask the same question here.
As we see in this Phet simulator, this is only the real part of the wave function, the frequency decreases with the potential, so lose energy as moves away the center.
we se this real-imaginary animation in Wikipedia, wave C,D,E,F. Because with less energy, the frequency of quantum wave...
These are the experimental results for the energy levels of Samarium-154:
From 0+ to 8+ I recognize rotational energy:
$$E = \frac{l(l+1)\hbar^2}{2I}$$
But from there on I do not know how to justify the rest.
I have been reading that we sometimes get energy diagrams like above for even-even...
I have been studying about the physiology of hunger. I have studied about the hormones that are involved in the process of hunger, like ghrelin, leptin, pancreatic polypeptide, cholecystokinin, cholecystokinin (CCK) and the neurons like AgRP, POMC and neuropeptide Y (NPY) etc.
I understand...
Homework Statement
I'm having trouble understanding the existence of valence shells.
I understood that valence shell is the last energy level for the electrons to populate around an atom.
But, according to Bohr model , an atom can have infinite energy levels , so I don't understand:
How can...
The basis of the question is: in creating a mist that you sprayed on a surface could you get an energy
transfer to the surface equivalent to an optical emission in the infrared? (Far Infrared).
How much energy is imparted to room temp water in creating a spray of particles around 5 microns...
Homework Statement
Homework Equations
The Attempt at a Solution
I understand the equation, and I understand the concept. My question is this: What is the best way to go about solving this problem? My line of reasoning concludes that the fourth lowest energy level is E211. However, the...
The figure below is from a textbook. It is explaining what excited states are using carbon as an example. I don't necessarily agree that the the state labeled as "example excited state 1" is really an excited state. Since the electrons in the 2p orbitals are unpaired, and in the absence of a...
It doesn't make sense to me that absorption spectra are (mostly) continuous.
Here are my beliefs. Please tell me which piece/pieces is a/are misconception(s).
1) When light is absorbed, the energy is used to excite an electron to some discrete energy level.
2) To get to this discrete energy...
I've noticed that in the Shell Model of the nucleus, the order of the energy levels is 1s, 1p3/2, 1p1/2, etc. While in the atomic energy levels it goes 1S 2S 2P, ... But they still take the same amount of particles for each level in both the atomic and nucleus.
Am I missing something here? Or...
Which are main absorption modes of matter for gamma rays under about 500 MeV? And how strong is the absorption?
For low energies (under 20 MeV) the mechanisms are:
1) Photoelectric absorption - all energies from eV range onwards
2) Compton scattering - all energies enough to displace the...
[Mentors' note: Moved from the technical forums, so no template]
Hi,
I have to find energy levels of an electron in a cylindrical shape. I know how to derive the formula below:
However, I'm not sure which zero value and what intger p I need to use in order to find the lowest energy.
If these...
Homework Statement
a) Draw a diagram of energy levels to explain the spectrum of lines of the hydrogen atom
b) Indicate, for each photon, that its region can be emitted to the electromagnetic spectrum.
c) Compare, in a graph, the energies of the orbital of the hydrogen atom with the energies of...
Homework Statement
If a system comprised only of two electrons was physically possible (such as positronium but with two electrons), what would its energy levels be and how would they relate to the energy levels of Helium?
Homework Equations
##E_{Helium} = E_{n1}+E_{n2}=-\frac{\mu Z^2...
I was wondering about the filament colors in a plasma ball that I have got. The main part of each filament is blue, but its end part is pink. Possibly the gas is 95% neon and 5% xenon, the pink part is light emitted by neon, and blue part light emitted by xenon. Using a hand spectroscope I...