Finding Nodal Surfaces in Wave Function of H-Like Atom

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Homework Help Overview

The discussion revolves around determining the number of nodal surfaces in the wave function of a hydrogen-like atom, specifically analyzing a given wave function expressed in polar coordinates.

Discussion Character

  • Conceptual clarification, Assumption checking, Exploratory

Approaches and Questions Raised

  • Participants explore the relationship between the quantum numbers and the number of nodal surfaces, with some suggesting that the absence of a phi component indicates a specific type of orbital. Others express a desire to visualize the wave function using MATLAB, questioning how to plot it.

Discussion Status

The discussion is ongoing, with participants sharing insights about the quantum numbers associated with the wave function and the implications for nodal surfaces. Some guidance on the structure of wave functions is provided, but no consensus has been reached regarding the specific number of nodal surfaces.

Contextual Notes

Participants note the challenge of answering the question quickly and the potential need for additional information or tools to visualize the wave function effectively.

ritwik06
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Homework Statement



One wave function of H like atom is [tex]\psi=\frac{\sqrt{2}}{81\sqrt{\pi}a_{0}^{3/2}}(6-\frac{r}{a_{0}})\frac{r}{a_{0}}(e^{\frac{-r}{3a_{0}}})cos \theta[/tex]

How many nodal surfaces are there?
1)1
2)2
3)3
4)none of these

The Attempt at a Solution


Its an objective question which I need to answer in less than a minute. Is it possible to do so?

The next thing that I assume i that the wave function is given in polar coordinate form, isn't it?? [tex]\psi=f(r,\theta, \phi)[/tex]?
phi is absent what does it mean? I guess it means that its the p - orbital. then the anwer must be 2. Am I right?

Last but not the least. I am keen upon seeing the 3D picture this wave function generates. I have MATLAB but I don't know how to code in polar coordinate and all. Will somebody code this wave function for me which is compatible with MATLAB 2008?? Please. I shall be very grateful.
Thanks a lot.
 
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Isn't the number of nodal surfaces equal to the quantum number of your wave function?
 
buffordboy23 said:
Isn't the number of nodal surfaces equal to the quantum number of your wave function?

Thanks a lot but I know that already. Is it of any help with this particular problem?
And sir, can you please tell me how can I plot equations such as this one and like
x2+y2+z2=1 with MATLAB?
 
Your given the wave function. The wave functions for the hydrogen atom are constructed from two separate functions, the spherical harmonic wave functions, [tex]Y^{m}_{l}\left(\theta,\phi\right)[/tex], and the radial wave functions, [tex]R_{nl}\left(r\right)[/tex]:

[tex]\Psi_{nlm}\left(r,\theta,\phi\right) = R_{nl}\left(r\right)Y^{m}_{l}\left(\theta,\phi\right)[/tex]

You really only need to look at the radial wave equation, since by definition it has a term [tex]e^{-r/na}[/tex], where n is the quantum number. So, this is easily determined by your given function.

I am pretty certain that n,l,m = 3,1,0 for your given wave function. Here's an applet to check out the probability density:

http://www.phy.davidson.edu/StuHome/cabell_f/Density.html
 

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