Finding the change in the eigenvalue without knowing the change in the

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SUMMARY

The discussion centers on the application of the Hellmann-Feynman theorem in quantum mechanics, specifically regarding the computation of the derivative of an eigenvalue, denoted as \(\frac{do(λ)}{dλ}\), without needing to know the change in the eigenstate \(\frac{d|\psi(λ)>}{dλ}\). The operator \(O(λ)\) must be Hermitian for the theorem to apply. Additionally, it is concluded that \(O(λ)\) commutes with \(O(λ')\) primarily in cases of degenerate eigenvalues.

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JBrandonS
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Hello,

I am currently teaching myself quantum mechanics using MIT's OCW and am suck on the following problem from the second problem set of the 2005 7.43 class.

Homework Statement



Consider an operator O that depends on a parameter λ and consider the λ-dependent eigenvalue equation:
O(λ)| \psi(λ) > = o(λ) | \psi(λ) >

Show that one can compute \frac{do(λ)}{dλ} without knowing \frac{d|\psi(λ)>}{dλ}. Thus one can determine the change in the eigenvalue without knowing the change in the eigenstate.

Under what conditions would O(λ) commute with O(λ')

Homework Equations





The Attempt at a Solution



I really have no idea where to begin on this one.
 
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JBrandonS said:
Hello,

I am currently teaching myself quantum mechanics using MIT's OCW and am suck on the following problem from the second problem set of the 2005 7.43 class.

Homework Statement



Consider an operator O that depends on a parameter λ and consider the λ-dependent eigenvalue equation:
O(λ)| \psi(λ) > = o(λ) | \psi(λ) >

Show that one can compute \frac{do(λ)}{dλ} without knowing \frac{d|\psi(λ)>}{dλ}. Thus one can determine the change in the eigenvalue without knowing the change in the eigenstate.

Under what conditions would O(λ) commute with O(λ')

Homework Equations


The Attempt at a Solution



I really have no idea where to begin on this one.

The first question looks like the Hellmann-Feynman theorem. Multiply by ##<\psi(λ)|## on the left and take the derivative and I think you need O to be Hermitian. Really not sure about the second half.
 
Last edited:
Dick said:
The first question looks like the Hellmann-Feynman theorem. Multiply by ##<\psi(λ)|## on the left and take the derivative and I think you need O to be Hermitian. Really not sure about the second half.

Thank you, like most of these problems it became really easy once I got a push. Took about 30 seconds to show.

I also believe the only case where O(λ) would commute with O(λ') would be for degenerate eigenvalues, but maybe someone else can chime in and let me know if that is right or wrong.
 

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