Finding the eigen function for an infinite square well (quantum mechanics)

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SUMMARY

The discussion focuses on calculating the wavelength and energy of a photon emitted during a transition of a proton in an infinite square well of length 10^-5 nm, specifically from the first excited state (n=2) to the ground state (n=1). The time-independent Schrödinger equation is utilized, leading to the differential equation \(\frac{d^2\psi}{dx^2} + k^2\psi = 0\), where \(k^2 = \frac{2mE}{\hbar}\). The solution involves oscillatory functions, and the participant expresses confusion regarding the application of boundary conditions and the significance of quantum numbers in this context.

PREREQUISITES
  • Understanding of the time-independent Schrödinger equation
  • Familiarity with quantum mechanics concepts such as eigenfunctions and quantum states
  • Knowledge of differential equations, particularly second-order linear equations
  • Basic principles of the electromagnetic spectrum and photon emission
NEXT STEPS
  • Study the solutions to the time-independent Schrödinger equation for infinite potential wells
  • Learn about the quantization of energy levels in quantum mechanics
  • Explore the relationship between quantum numbers and wavefunctions in quantum systems
  • Investigate the calculation of photon energy using the formula \(E = hf\) and its relation to wavelength
USEFUL FOR

Students and professionals in physics, particularly those studying quantum mechanics, as well as educators looking for insights into teaching concepts related to wavefunctions and energy transitions in quantum systems.

ElijahRockers
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Homework Statement



Quantum mechanics is absolutely confusing me.

A proton is confined in an infinite square well of length 10-5nm.

Calculate the wavelength and energy associated with the photon that is emitted when the proton undergoes a transition from the first excited state (n=2) to the ground state (n=1).

In what region of the electromagnetic spectrum does this wavelength belong?

The Attempt at a Solution



I'm not really sure what I'm doing at all.

But I started with the time independent Schrödinger equation. For region I and III, (where the potential is infinite) then the eigenfunction must be 0.

So I put in a potential of zero for the second region and got

\frac{d^2\psi}{dx^2} + k^2\psi = 0 where k^2 = \frac{2mE}{\hbar}

Looks like a second order diff eq, so I tried to solve it. Solutions to the characteristic equation were ±ik...

From here I am a little stumped, I didn't take notes, and I can't remember what the solution was that he used in class.

But anyway if I'm just going by my normal diff eq understanding,

\psi = Acos(kx)+Bsin(kx)

What's throwing me off is that I recall he had exponential solutions with imaginary components in them. These would oscillate, and so does my solution, but even if I had my solution in his form, what next?

Where does the length of the well come into play? What does n=2 -> n=1 mean?
Am I making this more complicated than it should be?
 
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