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I Finding the vibrational partition function of a diatomic molecule

  1. Mar 27, 2016 #1
    How did they break down the following summation?
    Screen Shot 2016-03-27 at 18.46.06.png
    When finding the vibrational partition function ofa diatomic molecule it was approximated that the energy levels of the vibrational part of the diatomic molecule were harmonic and therefore the energy equation for a harmonic oscillator was used. Is the summation made to equal (1 - exp( - hw/KbT))^-1 because there are two degrees of vibrational freedom and therefore two energy levels? Or isit just due to maths?
  2. jcsd
  3. Mar 27, 2016 #2


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    Staff: Mentor

    It's just the math:
    \sum_{n=0}^{\infty} x^n = \frac{1}{1 -x}
    for ##|x|<1##.
  4. Mar 28, 2016 #3
    Omg, thank you!
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