Fractioned electrons, what do they mean?

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Homework Help Overview

The discussion revolves around a problem involving excess electrons on a lead sphere, specifically calculating the number of excess electrons and the average number of excess electrons per lead atom. The context includes concepts of electric charge, quantization of charge, and atomic structure.

Discussion Character

  • Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • Participants discuss the calculation of excess electrons based on the net charge and the charge of an electron. There is confusion regarding the interpretation of fractional electrons per atom, with some questioning the physical meaning of having a non-integer number of excess electrons per atom.

Discussion Status

Participants are actively exploring the implications of their calculations, particularly the concept of fractional electrons. Some have provided calculations and references to support their findings, while others are seeking clarification on the meaning of these results. There is no explicit consensus on the interpretation of fractional electrons.

Contextual Notes

One participant noted a correction in the charge value used in the calculations, which may affect the understanding of the problem. The discussion reflects a mix of numerical and conceptual challenges related to the quantization of charge and atomic structure.

Raul Trejo
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Homework Statement


Excess electrons are placed on a small lead sphere with mass 8.00g so that it's net charge is -3.20x10^-9C (a) Find the number of excess electrons on the sphere. (b) how many excess electrons are there per lead atom? The atomic number of lead is 82, and its atomic mass is 207g/mol.

Homework Equations


We have -3.20x10^-9C . All charge is "quantized" meaning it is an integer multiple of the charge "e" (-1.602x10^-19C/electron). To obtain the amount of "excess" (Neutrally charged atoms have the same amount of protons and electrons, so a negatively charged atom has more electrons, the charge is due to theses extra electrons) we divide our charge Q by e. Electrons= (-3.20x10^-9C)/(-1.602x10^-19C/electron)=1.997x10^10 which we round to 2x10^10 electrons. We then obtain the number of moles the lead ball has, multiply it by avodagro's number to obtain the amount of atoms, and then divide the amount of electrons by the amount of atoms.And we end up with 8.594x10^-13electrons/atom.[/B]

The Attempt at a Solution



I can't get my head around the fact that 8.59x10-13 electrons is not an integer multiple of 1 electron. What does it even mean to have https://www4c.wolframalpha.com/Calculate/MSP/MSP157620gi5hegf6iihfdf00005if81hhidie84ia2?MSPStoreType=image/gif&s=59 extra electrons per atom? My understanding is that electrons are moved(transfered from one atom to the next) in integers, you can't really divide an electron to have 8.59x10^-13 of it. What does this actually mean?
 
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Raul Trejo said:

Homework Statement


Excess electrons are placed on a small lead sphere with mass 8.00g so that it's net charge is -3.20x10^-19C (a) Find the number of excess electrons on the sphere. (b) how many excess electrons are there per lead atom? The atomic number of lead is 82, and its atomic mass is 207g/mol.

Homework Equations

The Attempt at a Solution


The problem I'm having isn't numerical in sense. The answer to the part a is 2x10^10 electrons, but the answer to part (B) is 8.59x10^-13 electrons/atom. I can't get my head around the fact that 8.59x10-13 electrons is not an integer multiple of 1 electron. What does it even mean to have https://www4c.wolframalpha.com/Calculate/MSP/MSP157620gi5hegf6iihfdf00005if81hhidie84ia2?MSPStoreType=image/gif&s=59 extra electrons per atom? My understanding is that electrons are moved(transfered from one atom to the next) in integers, you can't really divide an electron to have 8.59x10^-13 of it. What does this actually mean?
It's not clear how you got your answer for (a). There is a definite electric charge per electron.

Can you post all of your calculations?
 
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SteamKing said:
It's not clear how you got your answer for (a). There is a definite electric charge per electron.

Can you post all of your calculations?
Note: I just realized I put -3.20x10^-19C, it's actually 10^-9.
We have -3.20x10^-9C . All charge is "quantized" meaning it is an integer multiple of the charge "e" (-1.602x10^-19C/electron). To obtain the amount of "excess" (Neutrally charged atoms have the same amount of protons and electrons, so a negatively charged atom has more electrons, the charge is due to theses extra electrons) we divide our charge Q by e. Electrons= (-3.20x10^-9C)/(-1.602x10^-19C/electron)=1.997x10^10 which we round to 2x10^10 electrons. We then obtain the number of moles the lead ball has, multiply it by avodagro's number to obtain the amount of atoms, and then divide the amount of electrons by the amount of atoms.And we end up with 8.594x10^-13electrons/atom. The answer is correct, I've checked it (Sears and Zemansky's University Physics with Modern Physics, problem 21.1). The question is, what does the fraction electrons really mean? What does it mean to have https://www4c.wolframalpha.com/Calculate/MSP/MSP157620gi5hegf6iihfdf00005if81hhidie84ia2?MSPStoreType=image/gif&s=59 electrons extra per atom? because you can't add only a fraction of an electron to an atom.
 
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Raul Trejo said:
Note: I just realized I put -3.20x10^-19C, it's actually 10^-9.
We have -3.20x10^-9C . All charge is "quantized" meaning it is an integer multiple of the charge "e" (-1.602x10^-19C/electron). To obtain the amount of "excess" (Neutrally charged atoms have the same amount of protons and electrons, so a negatively charged atom has more electrons, the charge is due to theses extra electrons) we divide our charge Q by e. Electrons= (-3.20x10^-9C)/(-1.602x10^-19C/electron)=1.997x10^10 which we round to 2x10^10 electrons. We then obtain the number of moles the lead ball has, multiply it by avodagro's number to obtain the amount of atoms, and then divide the amount of electrons by the amount of atoms.And we end up with 8.594x10^-13electrons/atom. The answer is correct, I've checked it (Sears and Zemansky's University Physics with Modern Physics, problem 21.1). The question is, what does the fraction electrons really mean? What does it mean to have https://www4c.wolframalpha.com/Calculate/MSP/MSP157620gi5hegf6iihfdf00005if81hhidie84ia2?MSPStoreType=image/gif&s=59 electrons extra per atom? because you can't add only a fraction of an electron to an atom.

You've got so many excess electrons and so many atoms on which to distribute these electrons. Having a fraction of an electron doesn't really mean anything, IMO.
 
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Raul Trejo said:
What does it mean to have
00005if81hhidie84ia2%3FMSPStoreType%3Dimage%2Fgif%26s%3D59&hash=11656f3b4753bb02e89d8bfcc98697ef.png
electrons extra per atom?
If you eat an apple each day, how many apples per second do you eat? It is just expressing an average.
 

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