Free electron or empty lattice schrodinger equation solution

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Homework Help Overview

The discussion revolves around the Schrödinger equation solutions for free electrons, specifically focusing on the wave function representation and boundary conditions. Participants are exploring the implications of these conditions on the existence of wave functions and their normalization.

Discussion Character

  • Conceptual clarification, Assumption checking, Mathematical reasoning

Approaches and Questions Raised

  • The original poster attempts to clarify the boundary conditions used in the wave function solution and questions the implications of assuming certain limits for the wave function. Other participants discuss the nature of the wave function and the necessity of normalization, suggesting that a plane wave cannot represent a physical state without further considerations.

Discussion Status

Participants are actively questioning the assumptions regarding boundary and initial conditions, with some guidance offered on the nature of wave functions and the need for normalization. There is an acknowledgment of the limitations of the plane wave solution in describing physical states.

Contextual Notes

There is a mention of an impending midterm, indicating time constraints for the original poster. The discussion also touches on the mathematical properties of wave functions and their physical interpretations, which may not be fully resolved.

AL-Hassan Naser
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in the solution for free electron we start with

X(x) = A exp (ikx) + B exp (-ikx)

then using boundary conditions we eliminate B if the wave is traveling in the positive direction and vice versa
my questions are:
1. what is the boundary condition used?
2. is it X(-inf) = 0? because this would cancel out B and leave A
3. But then if we also assume that X(inf)=0 then A=0 so we have no wave function and cancel out the electron which is a fallacy

please help i have my midterm on sunday
 
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As this is a free electron, remember that if we were to take the integral ##\int_{-\infty}^{\infty} \mathrm{X}^{*}\mathrm{X} = 1##
 
X=Aexp(ikx)+Bexp(-ikx)
X*=Aexp(-ikx)+Bexp(ikx)
X.X*=A^2+B^2+AB[exp(-2ikx)+exp(2ikx)]
<XIX>=1
X(A^2+B^2) +[AB/2ik]*[exp(2ikx)-exp(-2ikx)] = 1

how can I solve that?!

please help me i am losing time
 
really guys I need help here
 
It's not so much a question of boundary conditions as one of initial condition. Taking k to be positive, then one case corresponds to a particle of wave number k traveling towards +x, the other to a particle of wave number k traveling towards -x. You then keep the solution that corresponds to the physical situation you want to describe, for instance a particle coming in from ##x = -\infty##.

As for the normalization, I don't know what superluminal had in mind, but a plane wave is not square integrable, and hence can't describe a physical state. For that, you need to build a wave packet by summing over a few plane waves.
 

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