Gas Effusion Rate Problem: He, Cl2, H2, Kr, Rn

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SUMMARY

The discussion centers on identifying a contaminating gas in a sample of N2 that effuses at 0.25 times the rate of N2. The relevant equation used is Rate x/Rate N2 = √(Mass N2/Mass x). The participant attempted calculations leading to a mass of x that exceeds 400, which does not match any of the provided options: He, Cl2, H2, Kr, Rn. Further analysis suggests that using the mass of nitrogen instead of N2 yields a mass of approximately 224, indicating a potential error in arithmetic rather than conceptual understanding.

PREREQUISITES
  • Understanding of Graham's Law of Effusion
  • Familiarity with molecular mass calculations
  • Basic algebra skills for manipulating equations
  • Knowledge of the properties of gases, specifically N2 and its contaminants
NEXT STEPS
  • Review Graham's Law of Effusion and its applications
  • Practice molecular mass calculations for various gases
  • Explore common contaminants in gas samples and their properties
  • Learn how to accurately perform and check arithmetic in chemistry problems
USEFUL FOR

Chemistry students, educators, and professionals involved in gas analysis or physical chemistry who seek to understand effusion rates and gas properties.

Navygal
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The Problem
A sample of N2 gas is contaminated with a gas. It is found that that contaminant effuses at 0.25 times the rate of N2. What is the contaminating gas?

Choices are: He, Cl2, H2, Kr, Rn

Homework Equations



Rate x/Rate N2 = (square root of:) Mass N2/Mass x

Where Rate x =0.25 Rate N2

The Attempt at a Solution



By plugging in the values I get a mass of x that is over 400, and none of the above choices weight that much

Another option I tried is using just Nitrogen instead of N2 which gives me Mass x = 224 which comes close to the 222 that I got. But I have a feeling that it's wrong and not sure how to justify my answer
Any help would be greatly appreciated
 
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Could you show what you did? I didn't get either of your answers.
 
Navygal said:
The Problem
A sample of N2 gas is contaminated with a gas. It is found that that contaminant effuses at 0.25 times the rate of N2. What is the contaminating gas?

Choices are: He, Cl2, H2, Kr, Rn

Homework Equations



Rate x/Rate N2 = (square root of:) Mass N2/Mass x

Where Rate x =0.25 Rate N2

The Attempt at a Solution



By plugging in the values I get a mass of x that is over 400, and none of the above choices weight that much

Another option I tried is using just Nitrogen instead of N2 which gives me Mass x = 224 which comes close to the 222 that I got. But I have a feeling that it's wrong and not sure how to justify my answer
Any help would be greatly appreciated

If you show us your actual math I'm sure the mistake will present itself. You have the right idea but the arithmetic is off.
 

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