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How do u derive a general formula (without undue approximations) to calculate the solubility of CaCO3(s) in a aqueous solution at any pH?
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The discussion focuses on deriving a general formula for calculating the solubility of calcium carbonate (CaCO3) in aqueous solutions at varying pH levels. Key components include the use of dissociation equilibria, solubility product constant (Kso), and the water ion product. The approach emphasizes the importance of charge balance and mass balances for carbonates and calcium to determine the concentration of calcium. Reference is made to specific equations in pH calculation lectures, particularly equations 9.11, 9.12, and 9.13, which provide essential insights.
PREREQUISITESChemists, environmental scientists, and students studying aqueous chemistry or carbonate chemistry will benefit from this discussion.