Gibbs Free Energy Homework: CaCO3 <-> CaO + CO2

Click For Summary
SUMMARY

The discussion centers on calculating the Gibbs Free Energy (ΔG) for the reaction CaCO3 <-> CaO + CO2 at 900K, where the equilibrium pressure of CO2 is 0.0423 atm. The calculated ΔG is 5656.3 cal/mol, and the equilibrium constant K is derived from the pressure value. The relationship between ΔG and K is established through the equation ΔG = -RTlnK, confirming that the equilibrium pressure directly influences the Gibbs Free Energy of the reaction.

PREREQUISITES
  • Understanding of Gibbs Free Energy and its significance in chemical reactions
  • Familiarity with the equation ΔG = -RTlnK
  • Knowledge of equilibrium concepts in thermodynamics
  • Ability to interpret standard Gibbs Free Energy of formation values from tables
NEXT STEPS
  • Study the derivation and applications of the equation ΔG = -RTlnK
  • Learn how to calculate standard Gibbs Free Energy of formation for various compounds
  • Explore the relationship between equilibrium constants and reaction favorability
  • Investigate the impact of temperature on Gibbs Free Energy and equilibrium constants
USEFUL FOR

Chemistry students, educators, and professionals involved in thermodynamics, particularly those studying reaction equilibria and Gibbs Free Energy calculations.

jin.cao
Messages
13
Reaction score
0

Homework Statement


CaCO3 <-> CaO + CO2
At 900K, equilibrium pressure of CO2 is 0.0423 atm. Calculate Gibbs Free energy of Reaction and K.

Homework Equations


delta G = -RTlnK

The Attempt at a Solution



delta G = 5656.3 cal/mol
K = 0.0423

I have a feeling that this is incorrect
Could someone confirm/clarify for me

Thanks
 
Physics news on Phys.org
I'm not sure what the pressure has to do with it..
 
The equilibrium pressure of CO2 is directly connected to the \Delta G of the reaction. If the forward reaction is strongly favored, the pressure is higher, and vice versa.
 
ok, but does the pressure have anything to do with the calculations?

delta G = [sum(delta G formation, products) - sum(delta G formation, reactants)]

which can all be calculated from table values.

Then the equation:

delta G = -RTlnK can be used to find K

is this correct?
 

Similar threads

  • · Replies 4 ·
Replies
4
Views
2K
  • · Replies 1 ·
Replies
1
Views
3K
Replies
1
Views
3K
  • · Replies 7 ·
Replies
7
Views
3K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 2 ·
Replies
2
Views
2K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 4 ·
Replies
4
Views
3K
Replies
1
Views
2K
  • · Replies 1 ·
Replies
1
Views
2K