Graphene Nobel winners discover new property of graphene

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    Graphene Property
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Discussion Overview

The discussion revolves around the recent discovery that positively charged hydrogen atoms, or protons, can pass through graphene. Participants explore the implications of this property for hydrogen extraction from the atmosphere and potential applications in energy generation, including fuel cells and desalination. The conversation includes theoretical considerations, practical challenges, and speculative ideas regarding the use of graphene in these contexts.

Discussion Character

  • Exploratory
  • Debate/contested
  • Technical explanation
  • Conceptual clarification

Main Points Raised

  • Some participants propose that a graphene filter could potentially extract hydrogen from the air and generate electricity, suggesting a novel energy source.
  • Others argue that the energy required to ionize the air may exceed the energy gained from burning the collected hydrogen.
  • Concerns are raised about the low concentration of hydrogen in the atmosphere, with estimates suggesting it is insufficient for practical energy generation.
  • One participant suggests that the discovery could be useful in acidic solutions, potentially allowing for the collection of H+ ions, although they express skepticism about the magnitude of the effect.
  • Another participant highlights the difference between protons and H2 molecules, questioning the feasibility of the proposed applications based on the nature of the particles involved.
  • There is speculation about the potential for using graphene in fuel cells, particularly in relation to overcoming issues with electrode and catalyst poisoning.
  • Some participants note the need for further exploration of materials handling challenges before any practical application can be realized.

Areas of Agreement / Disagreement

Participants express a range of views, with no consensus on the feasibility of using graphene for hydrogen extraction or energy generation. Disagreement exists regarding the practicality of the proposed applications and the implications of the discovery.

Contextual Notes

Limitations include uncertainties about the concentration of hydrogen in the atmosphere, the energy costs associated with ionization, and the technical challenges related to materials handling and application development.

rafeh1
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Researchers from the University of Manchester were surprised to find that positively charged hydrogen atoms - protons - can pass through it

http://www.independent.co.uk/news/s...redible-new-graphene-discoveries-9885425.html

Does that mean that a graphene filter could extract hydrogen out of thin air and then use it to generate electricity or even burn it. free energy at last? actually not free but free hydrogen generated in air by sun. Air flows thru graphene filter extracts hydrogen burns to make more air flow thru filter.. Am I missing some thing?
 
Physics news on Phys.org
Doubt it - first you have to ionize the air, which probably will take more energy than you'd get from burning the hydrogen you collect.
 
Not enough hydrogen in the air to make it worthwhile? Elsewhere on the web someone calculated that there is only enough hydrogen in the entire atmosphere to power a few cities for a year.
 
This could be useful in acidic solutions though - if the principle still works there. You could possibly create a diffusion barrier where the H+ ions in solutions can collect. I think it would probably be a small effect though, and pretty sure there's some issues with the SLOT here.
 
dipole said:
Doubt it - first you have to ionize the air, which probably will take more energy than you'd get from burning the hydrogen you collect.

well not according to Nobel laurate who invented graphene and is author of the paper. they seem more authoritative than anonymous internet comments

“In the atmosphere there is a certain amount of hydrogen and this hydrogen will end up on the other side [of graphene] in a reservoir. Then you can use this hydrogen-collected reservoir to burn it in the same fuel cell and make electricity,” said Professor Sir Andrei Geim of Manchester Univeristy.

0B7CA615000005DC-0-image-3_1417083457033.jpg

Sir Andre Geim (left) and Dr Konstantin Novoselov (right) who were awarded the Nobel Prize for Physics in 2010
..

“Essentially you pump your fuel from the atmosphere and get electricity out of this fuel, in principle. Before this paper, this wouldn’t even be speculation; it would be science fiction. At least our paper provides a guidance and proof that this kind of device is possible and doesn’t contradict to any known laws of nature,” Sir Andre added.
 
Yes, because scientists never make overly optimistic claims in order to generate publicity. Their discovery is that they found protons can pass through graphene - you do understand that there's a big difference between a proton and an H2 molecule, don't you?
 
I can't help wondering if this technology, along with zeolite compression technology to concentrate oxygen from air, might be applicable to desalinating seawater for human use. Are there enough free hydrogen ions romping around in water to make it possible?
 
dipole said:
Yes, because scientists never make overly optimistic claims in order to generate publicity. Their discovery is that they found protons can pass through graphene - you do understand that there's a big difference between a proton and an H2 molecule, don't you?

the quotes are of a nobel laureate not mine. If you would like to dispute Andrei Geim's physics credentials feel free. I think the implication this discovery is leading to is specific charged particles can be filtered thus leading to a charged circuit if a one way trap door can be created out of a graphene filter. Where the random motion of charged particles allows them in but a chemical trap door prevents them from leaving creating a capacitor that gets charged simply by exposure to air.
 
Hydrogen concentration in Earth's atmosphere is ~ 0.5 ppm; dissociated (monatomic H) is going to be orders of magnitude less; ionized less yet. Activity on one side of a semi-permeable membrane (the "fuel collection" side) is never going to exceed that of the source (atmospheric) side. There are some materials handling problems to be solved before this application is ready for any credible IPO on Wall Street. (NASDAQ? Sure --- they'll buy anything.)
 
  • #11
Bystander said:
Hydrogen concentration in Earth's atmosphere is ~ 0.5 ppm; dissociated (monatomic H) is going to be orders of magnitude less; ionized less yet. Activity on one side of a semi-permeable membrane (the "fuel collection" side) is never going to exceed that of the source (atmospheric) side. There are some materials handling problems to be solved before this application is ready for any credible IPO on Wall Street. (NASDAQ? Sure --- they'll buy anything.)

But if you go higher up in the Earth's atmosphere, the ppm of Hydrogen would probably be much better.

Furthermore, what about applications for fuel cells? Couldn't graphene function similarly to a Proton Exchange Membrane (PEM) if a current is supplied?
 
  • #12
sanman said:
But if you go higher up in the Earth's atmosphere, the ppm of Hydrogen would probably be much better.
And how do I get my process plant up there?
sanman said:
Furthermore, what about applications for fuel cells? Couldn't graphene function similarly to a Proton Exchange Membrane (PEM) if a current is supplied?
The fuel cell possibilities are worth exploring if only to get around electrode/catalyst poisoning problems.
 

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