Ground State Wave Function for Identical Spin 1/2 Particles in a Potential Well

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SUMMARY

The ground state wave function for two non-interacting identical spin 1/2 fermions in a potential well from x=0 to x=a must be antisymmetric under particle exchange. The wave function is expressed as \(\psi(r) \chi(s)\), where \(\chi\) represents the spinor. If the spin state is symmetric, the particles occupy a spin triplet state; if antisymmetric, they occupy a singlet state. The challenge lies in determining which component of the wave function—spatial or spin—must be antisymmetric to ensure compliance with the Pauli exclusion principle.

PREREQUISITES
  • Understanding of quantum mechanics principles, particularly fermions and the Pauli exclusion principle.
  • Familiarity with wave functions and their representations in quantum systems.
  • Knowledge of spin states, specifically the differences between singlet and triplet states.
  • Basic grasp of potential wells and their implications on particle behavior.
NEXT STEPS
  • Study the properties of antisymmetric wave functions in quantum mechanics.
  • Learn about the implications of the Pauli exclusion principle on identical particles.
  • Explore the concept of spin states in more detail, focusing on triplet and singlet configurations.
  • Investigate the mathematical formulation of wave functions in potential wells, particularly for fermions.
USEFUL FOR

Students and researchers in quantum mechanics, particularly those focusing on particle physics, quantum statistics, and the behavior of identical fermions in potential wells.

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Homework Statement


Find the wave function of the ground energy state for a system of two non-interacting, identical spin 1/2 particles in a potential well extending from x=0 to x=a. Don't forget to consider spin.

Homework Equations


The Attempt at a Solution



Since the particles are fermions, they must occupy a state that is antisymmetric with respect to particle exchange. Their wave function will be of the form \psi (r) \chi(s), where \chi is a spinor. Either the spatial part or the spin part of the wave function must be antisymmetric (and the other part must be symmetric). If the spin state is symmetric, then the particles will occupy a state in the spin triplet. Otherwise, they will occupy the singlet. At this point I am confused, however. How do we know which component of the wave function must be anti-symmetric (spatial or spin)? Moreover, if the particles are in the spin triplet, how do we know which of the three possible spin states corresponds to the lowest energy?
 
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Since we want the ground state, we want to put each particle into the single-particle state of lowest energy. So their single-particle spatial wave functions are the same. What does that tell you about spatial symmetry?
 

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