Half-Reactions in Zn + HCl Reaction

  • Thread starter Thread starter Kaneki123
  • Start date Start date
  • Tags Tags
    Hcl Reaction
Click For Summary
Half-reactions are essential for understanding oxidation and reduction in chemical reactions. In the reaction between zinc and hydrochloric acid, the half-reactions can be represented as follows: zinc is oxidized to zinc ions by losing two electrons (Zn = Zn^2+ + 2e-), while hydrochloric acid is reduced, with hydrogen ions gaining electrons to form hydrogen gas (2HCl + 2e- = 2Cl- + H2). The discussion highlights that in redox reactions, the focus should be on the entire compound rather than individual elements, as the whole molecule or ion participates in the reaction. Additionally, oxidation numbers are useful for tracking electron transfer but do not represent measurable properties of atoms. The oxidation state of hydrogen changes during the reaction, raising questions about whether hydrogen or the compound HCl is being reduced. In gas phase reactions, the behavior of HCl can be more straightforward, but in aqueous solutions, chloride ions often act as spectators.
Kaneki123
Messages
120
Reaction score
3
I do not have a clear concept about half-reactions...Can someone please give the half reactions for following reaction,
Zn^0 + 2H^1 Cl^-1 -----> Zn^+2 Cl2^-1 + H2^0
or Zn + HCl ----> ZnCl2 + H2
 
Chemistry news on Phys.org
"Half reaction" is used when you have to deal with oxidation/reduction reactions. Half reaction represents how electron is produced/consumed for reducing and oxidizing agent. So,
Zn = Zn2+ + 2e-
2HCl + 2e- = 2Cl- + H2
Add both equation and you will see.
 
  • Like
Likes Kaneki123
HAYAO said:
"Half reaction" is used when you have to deal with oxidation/reduction reactions. Half reaction represents how electron is produced/consumed for reducing and oxidizing agent. So,
Zn = Zn2+ + 2e-
2HCl + 2e- = 2Cl- + H2
Add both equation and you will see.
Also one more thing...In the given equation, the oxidation state of H is changed...So would we say that H is being reduced or its whole compound HCl is being reduced?
 
In water Cl- is just a spectator, it is H+ that reacts.

But in the gas phase, where only HCl is present I am ready to accept your statement as a correct. Pointing to an element in a compound and stating "this is what is being reduced/oxidized" is often questionable, as it is whole molecule/ion that undergoes the reaction. Yes, when we use oxidation numbers for redox reactions that how we think about the process, but oxidation numbers are just a accounting device designed for keeping track of electrons in the reaction. There is no property of an atom that we can measure to check its oxidation number.
 

Similar threads

  • · Replies 15 ·
Replies
15
Views
4K
  • · Replies 6 ·
Replies
6
Views
3K
  • · Replies 1 ·
Replies
1
Views
3K
  • · Replies 4 ·
Replies
4
Views
8K
  • · Replies 10 ·
Replies
10
Views
2K
Replies
4
Views
2K
  • · Replies 2 ·
Replies
2
Views
2K
  • · Replies 2 ·
Replies
2
Views
4K
Replies
5
Views
3K
  • · Replies 3 ·
Replies
3
Views
2K