Half-Reactions in Zn + HCl Reaction

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SUMMARY

The discussion focuses on the half-reactions involved in the redox reaction between zinc (Zn) and hydrochloric acid (HCl). The half-reactions are identified as Zn = Zn2+ + 2e- for oxidation and 2HCl + 2e- = 2Cl- + H2 for reduction. Participants clarify that while oxidation states can indicate changes, it is essential to consider the entire compound's behavior in reactions. The conversation emphasizes the importance of understanding electron transfer in oxidation/reduction processes.

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  • Understanding of oxidation and reduction reactions
  • Familiarity with half-reaction notation
  • Basic knowledge of oxidation states
  • Concept of electron transfer in chemical reactions
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  • Learn about oxidation states and their significance in chemical reactions
  • Explore the concept of spectator ions in chemical reactions
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Chemistry students, educators, and professionals interested in redox reactions, particularly those studying electrochemistry and reaction mechanisms.

Kaneki123
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I do not have a clear concept about half-reactions...Can someone please give the half reactions for following reaction,
Zn^0 + 2H^1 Cl^-1 -----> Zn^+2 Cl2^-1 + H2^0
or Zn + HCl ----> ZnCl2 + H2
 
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"Half reaction" is used when you have to deal with oxidation/reduction reactions. Half reaction represents how electron is produced/consumed for reducing and oxidizing agent. So,
Zn = Zn2+ + 2e-
2HCl + 2e- = 2Cl- + H2
Add both equation and you will see.
 
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HAYAO said:
"Half reaction" is used when you have to deal with oxidation/reduction reactions. Half reaction represents how electron is produced/consumed for reducing and oxidizing agent. So,
Zn = Zn2+ + 2e-
2HCl + 2e- = 2Cl- + H2
Add both equation and you will see.
Also one more thing...In the given equation, the oxidation state of H is changed...So would we say that H is being reduced or its whole compound HCl is being reduced?
 
In water Cl- is just a spectator, it is H+ that reacts.

But in the gas phase, where only HCl is present I am ready to accept your statement as a correct. Pointing to an element in a compound and stating "this is what is being reduced/oxidized" is often questionable, as it is whole molecule/ion that undergoes the reaction. Yes, when we use oxidation numbers for redox reactions that how we think about the process, but oxidation numbers are just a accounting device designed for keeping track of electrons in the reaction. There is no property of an atom that we can measure to check its oxidation number.
 

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