Having difficulty comprehending a problem in Peskin's text

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The discussion focuses on problem 5.4 (c) from Peskin's "An Introduction to Quantum Field Theory," specifically addressing the bound state of positronium represented as |B(k)⟩. The equation involves the p-orbital wavefunctions ψ_i(p), electron and positron creation operators a^{\dagger} and b^{\dagger}, and the 2x2 matrix Σ^i. The matrix Σ^i is crucial as it constructs the two-particle wavefunction in momentum space, clarifying its role in representing the positronium bound state.

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In his "an introduction to quantum field theory", problem 5.4 (c), he describes a bound state of positronium as [tex]|B(k)\rangle=\sqrt{2M}\int{\frac{d^{3}p}{(2\pi)^{3}}\psi_{i}(p)a^{\dagger}_{p+\frac{k}{2}}\Sigma^{i}b^{\dagger}_{-p+\frac{k}{2}}|0\rangle}[/tex]
where [itex]\psi_{i}(p)[/itex] are the p-orbtal wavefunctions in momentum space(i=1,2,3), [itex]a^{\dagger}[/itex]and [itex]b^{\dagger}[/itex] are electron and positron creation operator, [itex]\Sigma^{i}[/itex] is some 2 by 2 matrix. I don't understand where this [itex]\Sigma^{i}[/itex] comes from. LHS of the equation is just a ket, in this case shouldn't RHS be a superposition of kets? What should I make of [itex]\Sigma^{i}[/itex]?
 
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The wavefunction of the positronium bound state is a two-particle wavefunction, which is a function of both electron and positron coordinates. The matrix $\Sigma^i$ is used to represent the two-particle wavefunction in the momentum space representation. It is essentially a two by two matrix whose elements contain the momentum space wavefunction $\psi_i(p)$. The matrix $\Sigma^i$ is used to construct the two-particle wavefunction in the momentum space representation of the positronium bound state.
 

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