How Can I Safely Remove Sticky Residue from an HCl Bottle?

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SUMMARY

The discussion focuses on safely removing sticky residue from a bottle of 12 M hydrochloric acid (HCl). The residue is likely due to improper storage with volatile amines, specifically ammonium hydroxide, leading to the formation of amine chlorides. Participants recommend using hexanes followed by acetone for effective cleaning, particularly if the residue is grease or oil from vacuum pumps. Additionally, the presence of white crystals near the spout suggests contamination that may require careful handling.

PREREQUISITES
  • Understanding of chemical safety protocols when handling hydrochloric acid.
  • Familiarity with volatile amines and their effects on materials.
  • Knowledge of appropriate cleaning solvents such as hexanes and acetone.
  • Experience with laboratory storage practices for hazardous materials.
NEXT STEPS
  • Research safe handling procedures for hydrochloric acid and other corrosive substances.
  • Learn about the properties and risks associated with volatile amines.
  • Investigate the use of hexanes and acetone in laboratory cleaning applications.
  • Explore best practices for storing chemicals in laboratory environments to prevent contamination.
USEFUL FOR

Laboratory technicians, chemists, and safety officers involved in chemical handling and storage, particularly those dealing with corrosive substances and volatile compounds.

mishima
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I found an old bottle of 12 M HCl that has a sticky residue on the outside of the bottle. It had a discoloring effect on blue fabric. How can I safely remove this?
 
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I guess that was a little vague. I'm asking how to clean the bottle, not the fabric.

The bottle was inside an acid cabinet, but not a bag alone. It had white crystals near the spout.
 
Have you tried rinsing the bottle in water? White crystals might be amine chlorides. This would indicate that sometime during the bottle's history it was improperly stored with volatile amines... usually ammonium hydroxide. Sticky residues can be anything. If the lab uses vacuum pumps and the exhaust from those pumps is not ventilated properly, you can get volatiles from experiments (bad ju ju!) and vacuum pump oil inside someplace like the cabinet beneath a vented hood where acids like this are sometimes stored. In my experience, sticky substances are usually greases and oils from a pump and are best removed with something like hexanes followed by acetone.

YMMV
 
Probably leftover glue left after the label was peeled off. Some volatile vapours might had stuck to it, causing that discoloration.
 
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