How Can Wavelengths Help Determine the Constant A in Absorption Spectra?

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Homework Help Overview

The discussion revolves around determining the constant A in the context of absorption spectra, specifically using the wavelengths of two adjacent spectral lines at room temperature, 97.5 nm and 102.8 nm. The problem is situated within atomic energy levels and photon energy calculations.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning

Approaches and Questions Raised

  • Participants explore the relationship between wavelength and energy, questioning how to utilize the given wavelengths without knowing the specific atom involved. Some suggest writing equations based on photon energy and energy level transitions, while others consider the implications of assuming transitions from specific quantum states.

Discussion Status

The discussion is active, with various approaches being proposed to relate the wavelengths to the energy levels. Some participants have offered guidance on setting up equations based on the energy of photons, while others are exploring the assumptions regarding quantum states.

Contextual Notes

There is a noted lack of information regarding the atomic number or specific atom, which may impact the ability to fully resolve the problem. Participants are considering how this missing information affects their calculations and assumptions.

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An atom has energy levels En=-\frac{A}{n^2} where n is an integer and A is a constant.
Among the spectral lines that the atom can absorb at room temperature are two
adjacent lines with wavelengths 97.5 nm and 102.8 nm. Find the value of the constant
A in electron volts.

Initially I thought we can equate the coulomb force to the centripetal force but we are not told the atomic number or atom. Totally no clue, how is the wavelength useful when you do not know what atom it is?
 
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Energy of the photon absorbed or emitted is given by

E_n = \frac{hc}{\lambda} = A(1 - \frac{1}{n^2})

Smaller wave length will have larger energy.

Write down two equations for two wavelength and solve them to find A and n.
 
We can assume transition from n quantum state to n=1?
 
Since the spectral lines that the atom can absorb at room temperature are two
adjacent lines with wavelengths 97.5 nm and 102.8 nm, you have to find energies of
E_n and E_{n+1} with respect to the ground state.
 

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