How do amperometry methods detect current?

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hi! please help me about the detail about amperometry methods in detection of current. tQ
 
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mizpurpura, welcome to Physics Forums!

Have you visited wikipedia yet? There is a pretty good write-up about amperometry:

http://en.wikipedia.org/wiki/Amperometry

If, after studying that, you have further questions or doubts, come right back here and post your questions. Surely members here are willing to help you along your way to understanding. That's what we do.