How do copper oxide solar cells work?

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SUMMARY

Copper oxide solar cells utilize cuprous oxide (Cu2O) as a semiconductor, where the doping is primarily influenced by oxygen. Unlike traditional solar cells that rely on a PN-junction between two doped materials, copper oxide cells can function with copper electrodes, which are not semiconductors. The discussion highlights the unique properties of cuprous oxide and its role in solar energy conversion, emphasizing that oxygen acts as a dopant in this context. This understanding clarifies the operational principles of Schottky diode solar cells and their variations.

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TL;DR
Cuprous oxide - copper solar cells have not been doped, yet they work. What is going on, if no PN-junction exists here.
So basically, I‘ve always been told that solar cells work because of the PN-junction that exists between two doped materials. Then I‘d like to ask, how do solar cells work that use cuprous oxide - copper electrodes. The cuprous oxide acts as an semiconductor I guess? But It isn‘t doped, and the other electrode (copper) isn‘t even a semiconductor. I‘ve heard of Schottky diode solar cells, but even those require the semiconductor to be doped. So can someone please explain to me what exactly is going on here, and if there are other examples of this phenomenon.
 
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