How do I calculate the length of a bond?

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SUMMARY

The discussion focuses on calculating the length of a carbon-carbon bond in the compound C6H8 using principles from quantum mechanics and molecular physics. Participants suggest using the Particle In a Box theory as a more accurate method than the Bohr model for estimating bond lengths. The energy level change associated with the absorption of ultraviolet light at 357 nm is crucial for determining the bond length, as it relates to the energy states of the electrons involved. Additionally, typical bond energies for carbon-carbon bonds can provide comparative insights for estimation.

PREREQUISITES
  • Understanding of quantum mechanics principles, specifically the Particle In a Box theory
  • Familiarity with the Bohr model of the atom
  • Knowledge of bond energies for carbon-carbon bonds (single, double, triple)
  • Basic concepts of electron energy levels and transitions
NEXT STEPS
  • Research the Particle In a Box theory and its applications in molecular physics
  • Study the Bohr model and its limitations in predicting atomic and molecular properties
  • Explore typical bond energies for carbon-carbon bonds to understand their implications in molecular structure
  • Learn how to calculate energy transitions in electrons using the formula E = hc/λ
USEFUL FOR

Chemistry students, molecular physicists, and anyone interested in understanding the quantum mechanics behind molecular bonding and energy transitions.

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“In C6H8, the carbon atoms are connected in a chain. In a rough approximation, some electrons can be viewed as confined to a line with the length of this chain. C6H8 absorbs ultraviolet light with wavelength 357 nm, which causes an electron to change from the third lowest allowed energy to the fourth lowest allowed energy. Use this information to estimate the length in pm of a typical carbon-carbon bond in C6H8.”

I assume I could just calculate the radius of a carbon atom and multiply it by 2 to find a rough estimate of the length of a carbon-carbon bond. However, I don't know how to do this and I don't know the importance of the energy level change described in the problem. I'd really appreciate help understanding this. An equation (if one exists) would also be appreciated. I do know that radius = (n^2)(Bohr radius). Thanks!
 
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fizzicsdummy said:
“In C6H8, the carbon atoms are connected in a chain. In a rough approximation, some electrons can be viewed as confined to a line with the length of this chain. C6H8 absorbs ultraviolet light with wavelength 357 nm, which causes an electron to change from the third lowest allowed energy to the fourth lowest allowed energy. Use this information to estimate the length in pm of a typical carbon-carbon bond in C6H8.”

I assume I could just calculate the radius of a carbon atom and multiply it by 2 to find a rough estimate of the length of a carbon-carbon bond. However, I don't know how to do this and I don't know the importance of the energy level change described in the problem. I'd really appreciate help understanding this. An equation (if one exists) would also be appreciated. I do know that radius = (n^2)(Bohr radius). Thanks!

You can estimate the length of the bond by referring to the typical bond energies of carbon - carbon bonds e.g. single , double , triple and compare these with the energy of the wavelength given to you.

The other way is by using the Particle In a Box theory , this is better than using the Bohr model , however it depends on which class you are in.
 

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