How Do Isotope Tracers Determine Mixing Ratios in Water Samples?

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SUMMARY

The discussion focuses on determining the mixing ratios of two water samples using isotopic tracers, specifically δ18O-H2O values. Sample 1 has a δ18O-H2O of -1 per mil, while Sample 2 has a δ18O-H2O of -20 per mil. The resulting mixture has a δ18O-H2O of -15 per mil. By applying the Isotopic Mixing Equation and a Two-component Mixing Model, the fractions of water from Sample 1 and Sample 2 are calculated to be 26% and 74%, respectively.

PREREQUISITES
  • Understanding of isotopic notation (δ18O-H2O)
  • Familiarity with mixing equations in chemistry
  • Knowledge of Two-component Mixing Models
  • Basic algebra for isolating variables in equations
NEXT STEPS
  • Study the Isotopic Mixing Equation in detail
  • Explore Two-component Mixing Models in environmental science
  • Learn about the applications of isotopic tracers in hydrology
  • Investigate the significance of δ18O in climate studies
USEFUL FOR

Environmental scientists, hydrologists, and students studying isotopic analysis in water samples will benefit from this discussion.

geojon
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Homework Statement


Two water samples are mixed. Sample 1 has δ18O-H2O = -1(per mil), Sample 2 has δ18O-H2O = -20 (per mil), and the mixture has δ18O-H2O = -15 (per mil).

What fraction of water came from sample 1 and what fraction came from sample 2?
Assume that F = the fraction of the water that came from Sample 1
Assume that 1-F = the fraction of the water that came from Sample 2

Homework Equations


QT=Q1+Q2 where QT is total percent, and Q1 and Q2 are the percent contributions to the mixture from samples 1 and 2, respectively.

δ18OTQT = δ18O1Q118O2Q2

The Attempt at a Solution


I've uploaded my work...if I am using the write mixing equation for two endmembers, my problem really is then just isolating and solving for F. From there I can solve for F2
 

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@Greg Bernhardt I've used the Isotopic Mixing Equation: δ18OTQT = δ18O1Q118O2Q2 in order to solve it. It can also be solved using a Two-component Mixing Model, according to the equations: F2 = (δ18Omix18O1) / (δ18O218O1) ; F1 = 1 - F2
Using both equations, you find that the fraction of the sample coming from sample 1 is 0.26 (or 26%), and percent contribution from sample 2 is 0.74 (or 74%)
 

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